2012
DOI: 10.1016/j.jcrysgro.2012.01.041
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A facile route for the fabrication of CeO2 nanosheets via controlling the morphology of CeOHCO3 precursors

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Cited by 35 publications
(17 citation statements)
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“…orthorhombic and hexagonal. According to the degree of symmetry (higher symmetry, lower degree of ordering and higher free energy) and literature [20,21], the orthorhombic phase of CeCO 3 OH is more stable than its hexagonal phase. In general, in terms of the free energy and Ostwald ripening rule [22], the most stable crystal structure phase or intermediate state phase with lower nucleation barrier is preferred to emerge first and then transforms to the most stable phase.…”
Section: The Formation Mechanism Of Nanosheetsmentioning
confidence: 99%
“…orthorhombic and hexagonal. According to the degree of symmetry (higher symmetry, lower degree of ordering and higher free energy) and literature [20,21], the orthorhombic phase of CeCO 3 OH is more stable than its hexagonal phase. In general, in terms of the free energy and Ostwald ripening rule [22], the most stable crystal structure phase or intermediate state phase with lower nucleation barrier is preferred to emerge first and then transforms to the most stable phase.…”
Section: The Formation Mechanism Of Nanosheetsmentioning
confidence: 99%
“…[58] When the CO 2 SM dosage was 3 g/L, the CO 2 SM released less CO 2, EDA and EG through thermal decomposition, resulting in the less formation of CO 3 2À . On the other hand, Ce 3 + existed in the forms of [Ce(OH)(H 2 O) n-atoms in EDA with oxygen atoms in EG.…”
Section: Formation Mechanism Of Ceco 3 Oh Precursorsmentioning
confidence: 99%
“…Among various rare earth compounds, CeO 2 has attracted intense interest because of its favourable activities, some of which stem from the presence of oxygen vacancies. The useful properties of CeO 2 include its optical characteristics [2][3][4][5][6][7], oxygen storage capacity [8] and high thermal stability [9]. Due to these characteristics, CeO 2 has been extensively used in sensors [10][11][12][13], photocatalysts [14] and three-way catalysts [15].…”
Section: Introductionmentioning
confidence: 99%