This study provides a systematic
analysis of the transport and
magnetophoretic behavior of nanoscale zerovalent iron (nZVI) particles,
both bare and surface functionalized by poly(ethylene glycol) (PEG)
and carboxymethyl cellulose (CMC), after undergoing a chemical reaction.
Here, a simple and well-investigated chemical reaction of methyl orange
(MO) degradation by nZVI was used as a model reaction system, and
the sand column transport and low-gradient magnetophoretic profiles
of the nanoparticles were measured before and after the reaction.
The results were compared over time and analyzed in the context of
extended Derjaguin–Landau–Verwey–Overbeek (DLVO)
theory to understand the particle interactions involved. The colloidal
stability of both bare and functionalized nZVI particles was enhanced
after the reaction due to the consumption of metallic Fe content,
resulting in a significant drop in their magnetic properties. As a
result, they exhibited improved mobility across the sand column and
a slower magnetophoretic collection rate compared to the unreacted
particles. Here, the colloidal filtration theory (CFT) was employed
to analyze the transport behavior of nZVI particles across the packed
sand column. It has been observed that the surface properties of the
reacted functionalized particles changed, possibly due to the entrapment
of degraded products within the polymer adlayer. Moreover, quartz
crystal microbalance with dissipation (QCM-D) measurements were performed
to reveal the viscoelastic contribution of the adlayer formed by both
bare and functionalized nZVI particles after the reaction on influencing
their transport behavior across the sand column. Finally, we proposed
the implementation of a high-gradient magnetic trap (HGMT) to reduce
the transport distance of the colloidally stable CMC-nZVI, both before
and after the reaction. This study sheds light on the behavioral changes
of iron nanoparticles after the reaction and highlights environmental
concerns regarding the presence of reacted nanoparticles.