Because of the shortcomings of traditional infrared-polarization image fusion algorithm, such as low intelligence and single optimization index, this paper proposes an intelligent infrared-polarization image fusion optimization algorithm based on fireworks algorithm. Firstly, an improved differential image correction method based on single pixel nonuniformity is proposed to remove the cold reflection. The two-dimensional discrete cosine transform (DCT) is used to reduce the image sensitivity and improve the robustness, and the Stokes vector formula is used to obtain the polarization characteristic image. Secondly, based on the strong complementarity between infrared-intensity image and degree of linear-polarization (DOLP) image and the explosive optimization of fireworks algorithm, the problem model of weighted fusion algorithm is established, and the fitness function based on root mean square error (RMSE) is constructed to calculate the optimal weight of source image. In the fusion experiment of long-wave infrared-intensity image and DOLP image, this method is compared with the common fusion algorithms. The results show that this method can effectively fuse the infrared-intensity and degree of polarization information, and the evaluation indexes of standard deviation, spatial frequency, mutual information, structural similarity, peak signal-to-noise ratio and information entropy of the fusion image are better than the comparison algorithm. In the future, cooperated with the long-wave infrared-polarization imaging system, this method can be applied to improve the infrared detection ability in complex environment.