A freestanding polypyrrole hybrid electrode supported by conducting silk fabric coated with PEDOT:PSS and MWCNTs for high-performance supercapacitor

Sun, Chao; Li, Xin; Zhao, Jiaming; Cai, Zaisheng; Ge, Fengyan

doi:10.1016/j.electacta.2019.05.124

Cited by 43 publications

(19 citation statements)

References 57 publications

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“…Then, the volumetric energy density (E) and power density were calculated according to the equations of (4) and (5). The PZCC-2-SCs can provide an energy density of 45.51 mWh cm −3 at a power density of 174.67 mW cm −3 , which is higher than previous report [ 53 , 54 ], suggesting the potential application in energy storage area.…”

Section: Resultsmentioning

confidence: 59%

“…Besides, the comparative CV and GCD profiles of PC, PZCC-1, and PZCC-2 electrode materials at a scan rate of 5 mV −1 and a current density of 0.2 A·g −1 are shown in Figure 7 , which can make it easier to see the significant differences and different reaction systems that also affect the PPy hybrid electrode materials. Compared to other CPs-based composites [ 47 , 48 , 49 , 50 , 51 , 52 , 53 , 54 ], the prepared electrode has better specific capacitance, which shows that this method is superior. The results indicate that the incorporation of ZIF-67 derived oxyhydroxide can improve the interface between CFs and PPy, which is beneficial to anchor the electrode material for more excellent electrochemical performance.…”

Section: Resultsmentioning

confidence: 93%

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Integrated Conductive Hybrid Electrode Materials Based on PPy@ZIF-67-Derived Oxyhydroxide@CFs Composites for Energy Storage

Yang

Qian

2021

Polymers

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Due to excellent flexibility and hydrophilicity, cellulose fibers (CFs) have become one of the most potential substrate materials in flexible and wearable electronics. In previous work, we prepared cobalt oxyhydroxide with crystal defects modified polypyrrole (PPy)@CFs composites with good electrochemical performance. In this work, we redesigned the crystalline and nanoscale cobalt oxyhydroxide with zeolitic imidazolate frameworks-67 (ZIF-67) as precursor. The results showed that the PPy@ZIF-67 derived cobalt oxyhydroxide@CFs (PZCC) hybrid electrode materials possess far better capacitance of 696.65 F·g−1 than those of PPy@CFs (308.75 F·g−1) and previous PPy@cobalt oxyhydroxide@CFs (571.3 F·g−1) at a current density of 0.2 A·g−1. The PZCC delivers an excellent cyclic stability (capacitance retention of 92.56%). Moreover, the PZCC-supercapacitors (SCs) can provide an energy density of 45.51 mWh cm−3 at a power density of 174.67 mWh·cm−3, suggesting the potential application in energy storage area.

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Section: Resultsmentioning

confidence: 59%

Section: Resultsmentioning

confidence: 93%

Integrated Conductive Hybrid Electrode Materials Based on PPy@ZIF-67-Derived Oxyhydroxide@CFs Composites for Energy Storage

Yang

Qian

2021

Polymers

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“…The production of ternary composites on SF templates from successive incorporation of additives represents another successful strategy that associates the outstanding conductivity and large pseudocapacitance with improvement in the cycling performance of the Electrical Double Layer Capacitance (EDLC) from additives to resulting devices. For this, hierarchical deposition of multiwalled carbon nanotubes (by drop coating) has been followed by the growth of a pseudocapacitive wrapping layer of poly(3,4-ethylene dioxy-thiophene)-poly(styrene sulfonat: PEDOT: PSS [45], polypyrrole [45] and polyaniline [46] or reduced graphene oxide/polyaniline (rGO/PANI) composites [47] on silk fibers that preserve the good mechanical properties of the fibers incorporating the high conductivity level of the conducting polymers.…”

Section: Energy Storage Solutionsmentioning

confidence: 99%

The State of the Art of Energy Harvesting and Storage in Silk Fibroin-Based Wearable and Implantable Devices

Lima¹,

Oliveira²

2020

Electrochem

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The energy autonomy of self-powered wearable electronics depends on the adequate development of new technologies for energy harvesting and energy storage devices based on textile fibers to facilitate the integration with truly flexible and wearable devices. Silk fiber-based systems are attractive for the design of biomedical devices, lithium-ion batteries and flexible supercapacitors, due to their nitrogen-rich structure (for preparation of hierarchical carbon-based structures), and available surface for chemical modification reinforcing electroactive properties for use in batteries and supercapacitors. Herein, this paper reviews recent advances on silk fiber-based systems for harvesting and the storage of energy and the corresponding strategies to reinforce the physical and chemical properties of the resulting composites applied as electrodes and battery separators.

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“…For wearable electronics, flexible supercapacitors can be significant energy storage devices of the future due to their outstanding advantages such as lightness, flexibility, high power density, long lifetime, safety, and fast charge/discharge rate 40‐45 . Production of the flexible carbon electrode materials derived from cotton fabric through thermal treatment in an inert atmosphere has been reported 46‐48 .…”

Section: Introductionmentioning

confidence: 99%

Boron‐doped porous carbon material derived from ZIF ‐11: Investigation of cotton fabric supercapacitor and Li‐ion battery performances

Buğday

Altın

Bulut

et al. 2022

Intl J of Energy Research

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Summary Nitrogen‐doped porous carbon (NPC@ZIF‐11) and boron‐NPC (BNPC@ZIF‐11) materials were synthesized by pyrolysis methods, and structural characterization of the compounds was carried out by scanning electron microscopy, transmission electron microscopy, Fourier‐transform infrared spectroscopy, X‐ray diffraction, Brunauer–Elmet–Teller technique, Raman spectroscopy, and inductively coupled plasma‐mass spectrometry techniques. The ZIF‐11 was converted to the NPC@ZIF11 by pyrolysis. BNPC@ZIF‐11 was fabricated from NPC@ZIF‐11 by pyrolysis in the presence of phenylboronic acid. The fabric supercapacitor, sandwich‐type supercapacitor, and Li‐ion battery performances of NPC@ZIF‐11 and BNPC@ZIF‐11 were investigated. The capacity of the Li‐ion cell was found as 720 mAh g−1 for the first cycle, and it was decreased to 250 mAh g−1 after 100 cycles. The capacitance values of the cylindrical devices were 92 F g−1 and 115.6 F g−1, for C1 and C4000 in KOH electrolytes. The BNPC@ZIF‐11 was used as an electrode material on cotton fabric, and the highest obtained capacitance was 72.8 mF for 0.1 mA, which is a promising result for wearable energy storage materials.

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A freestanding polypyrrole hybrid electrode supported by conducting silk fabric coated with PEDOT:PSS and MWCNTs for high-performance supercapacitor

Cited by 43 publications

References 57 publications

Integrated Conductive Hybrid Electrode Materials Based on PPy@ZIF-67-Derived Oxyhydroxide@CFs Composites for Energy Storage

Integrated Conductive Hybrid Electrode Materials Based on PPy@ZIF-67-Derived Oxyhydroxide@CFs Composites for Energy Storage

The State of the Art of Energy Harvesting and Storage in Silk Fibroin-Based Wearable and Implantable Devices

Boron‐doped porous carbon material derived from ZIF ‐11: Investigation of cotton fabric supercapacitor and Li‐ion battery performances

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