In this paper, the authors present an original solution to maximize the DC power collected in the case of a wireless power transfer (WPT) scenario. Using state-space model representation, the WPT System is considered as a feedback approach in order to maximize the amount of harvested energy. To do this, a global simulation is performed to show the importance of taking into account the propagation channel and the rectifier circuit aspects in the case of optimizing the waveform to increase the harvested energy. By using an optimized multisine signal with zero phase as the excitation, taking into account the characteristics of the channel and the physical contributions of the rectifier, we managed to obtain better output DC values compared to a single tone source or a multi-sine signal without optimization, with the same average power input.