Recently, Deutsch and Elizalde studied the largest and the smallest fixed points of permutations. Motivated by their work, we consider the analogous problems in set partitions. Let A n,k denote the number of partitions of {1, 2, . . . , n + 1} with the largest singleton {k + 1} for 0 ≤ k ≤ n. In this paper, several explicit formulas for A n,k , involving a Dobinski-type analog, are obtained by algebraic and combinatorial methods, many combinatorial identities involving A n,k and Bell numbers are presented by operator methods, and congruence properties of A n,k are also investigated. It will been showed that the sequences (A n+k,k ) n≥0 and (A n+k,k ) k≥0 (mod p) are periodic for any prime p, and contain a string of p − 1 consecutive zeroes. Moreover their minimum periods are conjectured to be N p = p p −1 p−1 for any prime p.