“…The photocatalytic mechanism of BiOXs/TiO 2 should proceed in the P–N junction heterostructure mechanism [33–35]. For the heterojunction, the electrons in the valence band (VB) of the BiOXs can be excited to the conduction band (CB) under visible light illumination, leaving holes (h + ) in the VB.…”
A new heterojunction BiOXs/TiO 2 photocatalyst was firstly prepared by a mixed solvothermal method. Several tools were used to characterise the structure and morphologies of as-obtained samples. The results of photocatalytic experiments indicated that flower-like BiOXs/TiO 2 fabricated by the thinner nanosheets exhibited excellent degradation properties towards methyl orange, bisphenol A and tetracycline under visible-light irradiation. The reasons could be the good absorption of organic pollutants and light, and the high separation efficiency of photogenic electrons and holes attributed to the construction of BiOXs/TiO 2 heterojunction with large special surface areas. The photocatalytic mechanism was proposed. This Letter could provide new ideas to design the visible-light catalysts.
“…The photocatalytic mechanism of BiOXs/TiO 2 should proceed in the P–N junction heterostructure mechanism [33–35]. For the heterojunction, the electrons in the valence band (VB) of the BiOXs can be excited to the conduction band (CB) under visible light illumination, leaving holes (h + ) in the VB.…”
A new heterojunction BiOXs/TiO 2 photocatalyst was firstly prepared by a mixed solvothermal method. Several tools were used to characterise the structure and morphologies of as-obtained samples. The results of photocatalytic experiments indicated that flower-like BiOXs/TiO 2 fabricated by the thinner nanosheets exhibited excellent degradation properties towards methyl orange, bisphenol A and tetracycline under visible-light irradiation. The reasons could be the good absorption of organic pollutants and light, and the high separation efficiency of photogenic electrons and holes attributed to the construction of BiOXs/TiO 2 heterojunction with large special surface areas. The photocatalytic mechanism was proposed. This Letter could provide new ideas to design the visible-light catalysts.
“…163 The third strategy is the successful establishment of a Zscheme mechanism that efficiently neutralizes the photogenerated hole accumulation in Cu 2 O, thus preventing its photooxidation. [168][169][170][171][172][173] The Liu group developed a hybrid photocatalyst where 2 nm Cu 2 O nanocrystals were uniformly photodeposited on oxygen vacancy containing 101-faceted octahedral TiO 2 nanocrystals (referred to as Cu 2 O/T1-V O ; Fig. 21a and b).…”
Section: Photocatalytic H 2 Evolution Reactionmentioning
In this review, we critically discuss the recent advances, developments and remaining challenges and future development on photocatalytic application of well-defined hybrid Cu2O nanostructures for organic reactions, H2 evolution and CO2 reduction.
“…11,12 Elemental doping is an effective way to decrease the semiconductor bandgap. [13][14][15] Nitrogen-doped (N-doped) TiO 2 has widely been used in photocatalytic water splitting, which showed efficient H 2 production under visible light irradiation by narrowing the bandgap energy of TiO 2 . 16,17 At the same time, application of cocatalyst was found to be effective in reducing the recombination of photo generated electron and holes.…”
Photocatalytic water splitting has been considered as one of the most promising methods to produce hydrogen as a source of clean fuel. Use of co-catalysts and elemental doping in TiO 2 has been extensively explored for effective photocatalysis. Here we report the synthesis of visible light responsive and Pt on the N-TiO 2 nanoparticles, showed much higher photocatalytic activity for hydrogen production than that prepared by the one-step method, where Co 3 O 4 is evenly dispersed in N-TiO 2 .The position of the co-catalyst Co 3 O 4 in TiO 2 has a significant effect on the photocatalytic properties of the prepared photocatalysts.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.