In situ and homogeneous hydrolysis of urea was utilized to design a homogeneous precipitation method to synthesize the ZnCr2O4 functional material. The as‐prepared nanospinel was systematically studied in terms of crystal structure, morphology, texture, and light absorption. A well‐crystalline single phase of ZnCr2O4 nanospinel with a spongy network structure was obtained. Transmission electron microscopy and X‐ray diffraction observations confirmed the formation of monocrystalline nanoparticles of ZnCr2O4 with the nanosize of 13 nm. The synthesized nanospinel showed a low direct band gap value of 1.8 eV with appropriate absorption in the visible light region, which was a remarkable result for this route.