R ecently, research on lightweight materials has been an essential aspect in aircraft manufacturing and aerospace industry. The γ-TiAl based alloys with high content of Nb are promising candidates as a new high temperature material due to their low density, excellent specific strength, specific stiffness, and good high temperature oxidation and creep resistance [1,2] . Compared with nickel-based superalloy, which has been widely used for more than fifty years, TiAl alloy containing high Nb is lighter in weight. The high Nb TiAl alloy exhibits superior creep properties and high temperature oxidation resistance compared to normal TiAl based alloy over 973 K [1][2][3][4][5][6][7][8][9] .TiAl-based alloys have high mechanical strength both at room and high temperatures because of their ordered structure, but single γ phase TiAl-based alloys have very low room temperature ductility. The near γ phase TiAl based alloy shows better ductility with the presence of a small amount of the second α 2 phase. The microstructure of the near γ phase is of α 2 -γ layered structure which is called full lamellar structure. The Abstract: Three novel multi-microalloying TiAl-based alloys containing high Nb were designed and fabricated.Thermogravimetric method was applied to investigate the influence of Cr on the oxidation behavior of high NbTiAl alloy at 1,073 K for 200 h in laboratory air. The 2at.% and 4at.% Cr were added into the alloy, (respectively named 2Cr and 4Cr compared to the Cr-free ternary alloy, 0Cr alloy). The alloys' microstructure and composition as well as the composition distribution of the oxidation scale were analyzed by means of Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), and X-Ray Diffractometry (XRD). The results show that the addition of Cr decreases the grain size of the Nb-TiAl alloy and leads to a transformation from a fully lamellar structure to a nearly fully lamellar structure. When oxidized at 1,073 K for 200 h, the oxidized mass gain of the alloy increases with an increase in Cr addition amount in the first 100 h and decreases in the last 100 h. With the increase of Cr content, the oxidation surface turns compact but uneven in morphology, which may affect the oxidation resistance of the alloy by increasing the peeling off risk of the oxidation layer at friction conditions. room temperature ductility of the near γ phase TiAl based alloy is closely related to the grain size and microstructure distribution. Small grain size and good grain boundary strength can significantly improve the toughness of the alloy. One of the most interesting approaches to decrease grain size is micro-multicomponent alloying, in which a variety of alloying elements are added in trace amounts. The near γ-phase TiAl-based alloys have very good solid solubility for many alloying elements, so micro-multi-component alloying is very effective for the microstructure optimization of the material. Alloying elements such as Cr, B, Si and W are usually added in the TiAl alloy. It has been found that the addit...