A high performance electrochemical sensor for carbendazim based on porous carbon with intrinsic defects

Liang, Wei; Huang, Xianghua; Yang, Jing; Wang, Yanli; Huang, Ke-Jing; Xie, Liping; Yan, Feiyan; Luo, Lihong; Jiang, Cuiwen; Liang, Jing; Li, Tao; Yu, Yan

doi:10.1016/j.jelechem.2022.116370

Cited by 12 publications

(3 citation statements)

References 54 publications

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“…Different carbon structures such as carbon spherical shells (CSS) [ 38 ], N-doped carbon (NC) [ 39 ], carbon nanofibers (CNFs) [ 40 , 41 , 42 ], porous carbon derivatives [ 43 , 44 ], carbon nanospheres (CNS) [ 45 ], and carbon nanohorns (CNH)s [ 46 ] have been used to develop electrochemical sensors for CBZ detection. Part of these materials allow LOD values below 1.0 nM with applications in food, water, and biological samples.…”

Section: Electrochemical Sensor For Cbz Detectionmentioning

confidence: 99%

Carbon-Based Electrochemical (Bio)sensors for the Detection of Carbendazim: A Review

Venegas,

Bollo,

Sierra-Rosales

2023

Micromachines

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Carbendazim, a fungicide widely used in agriculture, has been classified as a hazardous chemical by the World Health Organization due to its environmental persistence. It is prohibited in several countries; therefore, detecting it in food and environmental samples is highly necessary. A reliable, rapid, and low-cost method uses electrochemical sensors and biosensors, especially those modified with carbon-based materials with good analytical performance. In this review, we summarize the use of carbon-based electrochemical (bio)sensors for detecting carbendazim in environmental and food matrixes, with a particular interest in the role of carbon materials. Focus on publications between 2018 and 2023 that have been describing the use of carbon nanotubes, carbon nitride, graphene, and its derivatives, and carbon-based materials as modifiers, emphasizing the analytical performance obtained, such as linear range, detection limit, selectivity, and the matrix where the detection was applied.

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Section: Electrochemical Sensor For Cbz Detectionmentioning

confidence: 99%

Carbon-Based Electrochemical (Bio)sensors for the Detection of Carbendazim: A Review

Venegas,

Bollo,

Sierra-Rosales

2023

Micromachines

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“…However, these methods usually require expensive equipment, laborious procedures, skilled operators, and the use of large amounts of solvents that can be hazardous to human health. Alternatively, electroanalytical approaches that use modified electrodes appear to be simple, feasible, low-cost, and eco-friendly strategies for determining CBZ [11][12][13][14]. The quantification of low concentrations of pesticides using electrochemical methods commonly involves combining strategies of preconcentration and chemically modified electrodes (CMEs) [14][15][16][17][18][19].…”

Section: Introductionmentioning

confidence: 99%

Electrochemical determination of carbendazim in juice samples using carbon composite electrode modified with ion‐exchange resin

Papi,

Bergamini,

Marcolino‐Junior

2024

Electroanalysis

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“…And there are two kinds of smaller nitrate ion sensors, pen sensors and hand-held testers. In contrast, the detection method based on the electrochemical principle has the advantages of simple instrument, convenient operation, less reagents required, and easy integration with the detection circuit, which is considered to be a new type of nitrate detection method with great development prospects [11][12][13].…”

Section: Introductionmentioning

confidence: 99%

A Miniaturized Electrochemical Nitrate Sensor and the Design for Its Automatic Operation Based on Distributed Model

Zhenxing

2022

Mathematical Problems in Engineering

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As one of the most common inorganic ions in daily food and ecological environment, nitrate (NO3−) is potentially harmful to both environment and humans. Therefore, the detection of nitrate concentration is quite important. Chemical sensors, as analytical measurement tools, usually demonstrate high selectivity, fast analysis speed, simple structure, convenient operation, and low cost and are considered to be a promising method for ion identification and detection. In this paper, a miniaturized electrochemical electrode is fabricated based on the microfabrication technology, and an electrochemical sensor for the detection of nitrate concentration in water is developed by combining the deposition technology of nanometal particles with electrochemical analysis technique. The developed electrochemical sensor utilizes electrochemical deposition to prepare a copper (Cu) granular sensitive film with a branch-cluster structure on the surface of a circular working electrode (Pt). Using copper’s characteristics of electrocatalytic reduction of NO3− in the acid solution environment (pH = 2), the concentration of NO3− in the water sample was calculated by measuring the reduction current on the working electrode when the electrocatalytic reduction reaction of NO3− occurred on the surface of the copper-sensitive membrane. The sensitive film is characterized and detected both with the scanning electron microscope (SEM) and X-ray diffraction analysis (XRD) technique; and the microsensor is used to detect nitrate standard samples; a high detection sensitivity (24.9 μA/mmol·L−1) is achieved in the concentration range of 0.0 to 3.0 mmol/L. At the same time, a MEMS three-electrode sensor without gold wire bonding and insulating glue packaging is designed, and an automatic detection system is constructed with a STM32f103 microcontroller as the controller to realize the automated detecting process for nitrate ions. At the same time, a distributed system is constructed, which can describe the nitrate concentration in every position of the water area and realize the monitoring of the whole water area. The detection system can meet the working environment under most conditions and has practical significance.

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A high performance electrochemical sensor for carbendazim based on porous carbon with intrinsic defects

Cited by 12 publications

References 54 publications

Carbon-Based Electrochemical (Bio)sensors for the Detection of Carbendazim: A Review

Carbon-Based Electrochemical (Bio)sensors for the Detection of Carbendazim: A Review

Electrochemical determination of carbendazim in juice samples using carbon composite electrode modified with ion‐exchange resin

A Miniaturized Electrochemical Nitrate Sensor and the Design for Its Automatic Operation Based on Distributed Model

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