A high performance sulfur-doped disordered carbon anode for sodium ion batteries

Li, Wei; Zhou, Min; Li, Haomiao; Wang, Kangli; Cheng, Shijie; Jiang, Kai

doi:10.1039/c5ee01985k

Cited by 574 publications

(336 citation statements)

References 44 publications

(67 reference statements)

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“…In SC-BDSA, the peak at 212 cm −1 belongs to the S-S chain-structure, while the stretching vibrations of C-S backbone is located at ≈355 cm −1 . [22,42] All of the S 2p XPS spectra can be deconvoluted into four peaks, which correspond to SS/CS bonds at around 164/165 eV, and sulfate species at about 168/169 eV, respectively. Figure 2c displays the X-ray photoelectron spectroscopic (XPS) survey spectra of the SC-BDSA, C-BDSA, and C-BSA, which show the pronounced XPS O 1s, C 1s, S 2p, and S 2s peaks at about 534, 285, 228, and 165 eV.…”

Section: Preparation and Physical-chemistry Features Of Sulfurized-camentioning

confidence: 99%

Controllable Chain‐Length for Covalent Sulfur–Carbon Materials Enabling Stable and High‐Capacity Sodium Storage

Jing

Yang

et al. 2019

Advanced Energy Materials

159

120

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couple high-capacity sulfur positive electrodes with earth-abundant sodium negative electrodes are unsurprisingly considered as a promising candidate. [8][9][10][11] In the process of cycle, the elemental sulfur of the cathode is dissolvated, reduced to form various soluble polysulfides, that is, S x 2− ions and radicals (1 ≤ x ≤ 8), and eventually the insoluble Na 2 S 2 and Na 2 S. [8,10,12] However, the practical applications are seriously hindered by several obstacles, in which the fundamental challenges are originated from the insulating properties of elemental sulfur and sodium sulfides, the volume changes at the cathode on cycling and the dissolution of sodium poly sulfides in the electrolyte. [9,[13][14][15] To date, extensive efforts have been made toward the enhancement of RT-Na/S batteries, including Na 2 S cathodes, [16,17] carbonaceous buffer matrixes, [12,18,19] a class of sodium polysulfides, [20,21] and the functional carbon-coated Nafion separator. [22] These approaches, while are validated to improve the cyclability of the RT Na-S batteries, tend to result in complicated synthetic processes and decreased theoretical capacity. In addition, it was suggested that the polar-polar interaction is a strong chemical interaction between polar sodium polysulfides and polar host materials. [23,24] Although there is no universal conclusion on the exact configuration of the interactions due to the complexity of carbon matrix, their similar effect in suppressing the polysulfide shuttle has also been reported in Li-S battery systems. [25][26][27] Instead of relying on polar-polar interactions, the suitably tailored hosts can bind sodium polysulfides through metal-sulfur bonding. Examples of such materials are sub-stoichiometric metal chalcogenides, MXene phases and metal-organic frameworks (MOFs). [28][29][30][31] In practice, these oxide and sulfide materials are able to bridge sodium polysulfides through both polar-polar Na-S(O) interaction and Lewis acid-base bonding, depending on the exposed facets to some extent. [25,32] However, to simply increase metal and/or binder content only neutralizes the advantageous energy density of the overall cell. Moreover, most of the sulfur-carbon electrode materials are directly prepared using elemental S and various carbon matrixes as started materials through vapor-infiltration or meltinfusion method. [8,10] As a result, the aggregated particles are Room temperature sodium-sulfur batteries have emerged as promising candidate for application in energy storage. However, the electrodes are usually obtained through infusing elemental sulfur into various carbon sources, and the precipitation of insoluble and irreversible sulfide species on the surface of carbon and sodium readily leads to continuous capacity degradation. Here, a novel strategy is demonstrated to prepare a covalent sulfur-carbon complex (SC-BDSA) with high covalent-sulfur concentration (40.1%) that relies on SO 3 H (Benzenedisulfonic acid, BDSA) and SO 4 2− as the sulfur source rather than elemental sulfur. M...

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Section: Preparation and Physical-chemistry Features Of Sulfurized-camentioning

confidence: 99%

Controllable Chain‐Length for Covalent Sulfur–Carbon Materials Enabling Stable and High‐Capacity Sodium Storage

Jing

Yang

et al. 2019

Advanced Energy Materials

159

120

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“…Unfortunately, the radius of Na þ (0.102 nm) is larger than that of Li þ (0.076 nm), which makes it difficult to find an appropriate host material with sufficiently interstitial space to accommodate Na þ [7]. Graphite, the typical LIBs anode with highly ordered layer structure, has been studied as the SIBs anode, but the specific capacity is low as it cannot store sufficient Na þ between its layers [8,9]. Non-graphitic carbonaceous materials (e.g.…”

Section: Introductionmentioning

confidence: 99%

In situ X-ray diffraction characterization of NbS2 nanosheets as the anode material for sodium ion batteries

Xiong

Zheng

Yang

et al. 2016

Journal of Power Sources

112

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“…[ 138,269, The storage of Na in carbon materials such as hard carbon, amorphous carbon, defected graphene, and functionalized graphite has been observed to be thermodynamically feasible. [ 325,326,274,276 ] In the early works by Doeff et al, they demonstrated that the extent of Na intercalation in carbon materials varies depending on the carbon structure; NaC 70 , NaC 30 , and NaC 15 were formed for graphite, petroleum coke, and Shawinigan black, respectively.…”

Section: Non-graphitic Carbonmentioning

confidence: 99%

“…Later work by Chen et al revealed that the electrode operation involves a single-phase reaction with a negligible volume change (≈1.2%), resulting in a high rate and cycle performances. [ 138 ] Although various phosphate compounds have been introduced as new low-cost electrode materials for NIBs, they exhibit generally low energy densities below 400 Wh kg −1 and limited cycle stabilities.…”

Section: Phosphatesmentioning

confidence: 99%

Recent Progress in Electrode Materials for Sodium‐Ion Batteries

Kim

Zhang

et al. 2016

Advanced Energy Materials

884

595

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Grid‐scale energy storage systems (ESSs) that can connect to sustainable energy resources have received great attention in an effort to satisfy ever‐growing energy demands. Although recent advances in Li‐ion battery (LIB) technology have increased the energy density to a level applicable to grid‐scale ESSs, the high cost of Li and transition metals have led to a search for lower‐cost battery system alternatives. Based on the abundance and accessibility of Na and its similar electrochemistry to the well‐established LIB technology, Na‐ion batteries (NIBs) have attracted significant attention as an ideal candidate for grid‐scale ESSs. Since research on NIB chemistry resurged in 2010, various positive and negative electrode materials have been synthesized and evaluated for NIBs. Nonetheless, studies on NIB chemistry are still in their infancy compared with LIB technology, and further improvements are required in terms of energy, power density, and electrochemical stability for commercialization. Most recent progress on electrode materials for NIBs, including the discovery of new electrode materials and their Na storage mechanisms, is briefly reviewed. In addition, efforts to enhance the electrochemical properties of NIB electrode materials as well as the challenges and perspectives involving these materials are discussed.

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A high performance sulfur-doped disordered carbon anode for sodium ion batteries

Abstract: Sulfur-doped disordered carbon exhibits high capacity and excellent cyclability as an anode for sodium ion batteries.

Cited by 574 publications

References 44 publications

Controllable Chain‐Length for Covalent Sulfur–Carbon Materials Enabling Stable and High‐Capacity Sodium Storage

Controllable Chain‐Length for Covalent Sulfur–Carbon Materials Enabling Stable and High‐Capacity Sodium Storage

In situ X-ray diffraction characterization of NbS2 nanosheets as the anode material for sodium ion batteries

Recent Progress in Electrode Materials for Sodium‐Ion Batteries

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