Citation for published item:wolonyD eter uF nd qregoryD hilip hF nd tiD honghu nd vuD fo nd u¤ oppingerD wi h el F nd ve ueurD gF uth nd fl kleyD g roline vF nd rutsonD teremy wF nd gornishD imon vF @PHIRA 9gre tion of ultr old VU IQQgs mole ules in the rovi r tion l ground st teF9D hysi l review lettersFD IIQ @PSAF pF PSSQHIF Further information on publisher's website:httpXGGdxFdoiForgGIHFIIHQG hys evvettFIIQFPSSQHI Publisher's copyright statement:Reprinted with permission from the American Physical Society: Physical Review Letters 113, 255301 c 2014 by the American Physical Society. Readers may view, browse, and/or download material for temporary copying purposes only, provided these uses are for noncommercial personal purposes. Except as provided by law, this material may not be further reproduced, distributed, transmitted, modi ed, adapted, performed, displayed, published, or sold in whole or part, without prior written permission from the American Physical Society.Additional information:
Use policyThe full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-pro t purposes provided that:• a full bibliographic reference is made to the original source • a link is made to the metadata record in DRO • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders.Please consult the full DRO policy for further details. We report the creation of a sample of over 1000 ultracold 87 Rb 133 Cs molecules in the lowest rovibrational ground state, from an atomic mixture of 87 Rb and 133 Cs, by magnetoassociation on an interspecies Feshbach resonance followed by stimulated Raman adiabatic passage (STIRAP). We measure the binding energy of the RbCs molecule to be hc × 3811.576ð1Þ cm −1 and the jv 00 ¼ 0; J 00 ¼ 0i to jv 00 ¼ 0; J 00 ¼ 2i splitting to be h × 2940.09ð6Þ MHz. Stark spectroscopy of the rovibrational ground state yields an electric dipole moment of 1.225(3)(8) D, where the values in parentheses are the statistical and systematic uncertainties, respectively. We can access a space-fixed dipole moment of 0.355(2)(4) D, which is substantially higher than in previous work.