A High-Resolution Fourier Transform Infrared Study of the Out-of-Plane Bending Fundamentals of HCOCl and DCOCl

High-resolution cavity ring-down spectroscopy has been used to record three vibronic bands of the transition of room-temperature formyl chloride (HClCO). These three bands A 3 1AAÈX 3 1A@ (p* ^nO ) (6 0 1 , 5 0 1 6 0 1 and are all vibronically induced through the activity of the out-of-plane inversion vibration and 2 0 1 5 0 1 6 0 1) l 6 , are found to obey type-a selection rules. Rotational constants have been derived from the analysis of these bands and used to give information on the geometrical structure of the excited state. The properties of the A 3 state are found to be intermediate between those of the corresponding states of formaldehyde and formyl Ñuoride.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

A High-Resolution Fourier Transform Infrared Study of the Out-of-Plane Bending Fundamentals of HCOCl and DCOCl

Cited by 4 publications

References 19 publications

Kinetic and products study of the gas-phase reaction of Lewisite with ozone under atmospheric conditions

Kinetic and products study of the gas-phase reaction of Lewisite with ozone under atmospheric conditions

Ab initio anharmonic force field and ab initio and experimental equilibrium structures of formyl chloride

Rotational structure in the Ã1A″–X̃1A′ spectrum of formyl chloride

Contact Info

Product

Resources

About