Hydrogel-based electronic skin (E-skin) has attracted
great research
interest because of their promising applications in skin-attachable
devices for health monitoring, prosthetics, and robotics. However,
the design and fabrication of hydrogel-based E-skin devices with desirable
mechanical properties, alongside simultaneous high sensitivity and
a broad detection range, remains a significant challenge. In this
study, we successfully synthesize an integrated capacitive sensor
based on a gradient charge distribution hydrogel with a sandwich-like
structure (cation-rich layer, dielectric layer, and anion-rich layer).
This synthesis is accomplished via a process entailing the migration
of ions in solution under a high-voltage electrostatic field, followed
by UV curing. Fluorescent nanospheres are utilized to mimic ion motion,
as indicated by the alterations in fluorescence intensity and micromorphology
observed on both sides of the hydrogel. The capacitive sensor exhibits
impressive mechanical performance, with a compressive strength of
987 kPa at 70% compression strain. Besides, owing to the electrical
double layer (EDL) constructed by the ion gradient and the nanospine
structure fabricated on the hydrogel surface, the sensor achieves
both high sensitivity (increased by more than 20 times) and wide detection
range at the same time. Moreover, the flexible sensors demonstrate
fast response time (31 ms), allowing for immediate detection of both
subtle and robust physiological activities. This strategy provides
a convenient method to fabricate gradient-ion hydrogels and develops
the applications in monitoring subtle vital signals and human movements.