A luminescence spectroscopy study of SrI2:Nd3+ single crystals

Огородников, И. Н.; Пустоваров, В. А.; Goloshumova, A.A.; Исаенко, Л. И.; Yelisseyev, A.; Pashkov, V. M.

doi:10.1016/j.jlumin.2013.04.007

Cited by 12 publications

(4 citation statements)

References 34 publications

(40 reference statements)

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“…7 shows the energy of 4.1 70.15 eV reported for the CT-band of Nd 3 þ in Ref. [22]. Since the endpoint of the arrow is at the Nd 2 þ ground state, it confirms our assignment that the 295 nm band in Fig.…”

Section: Vacuum Referred Binding Energy Diagram Of the Lanthanide Ionsupporting

confidence: 86%

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Luminescence and spectroscopic properties of Sm2+ and Er3+ doped SrI2

Alekhin

Awater

Biner

et al. 2015

Journal of Luminescence

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Section: Vacuum Referred Binding Energy Diagram Of the Lanthanide Ionsupporting

confidence: 86%

“…7), E V ¼ À5.34 eV is obtained. Next, one needs the exciton creation energy E ex in SrI 2 which is well established from different sources [12,[20][21][22]. We use 5.5 eV (225 nm) that applies to an exciton creation at about 10 K, as indicated with arrow 2 in Fig.…”

Section: Vacuum Referred Binding Energy Diagram Of the Lanthanide Ionmentioning

confidence: 99%

Luminescence and spectroscopic properties of Sm2+ and Er3+ doped SrI2

Alekhin

Awater

Biner

et al. 2015

Journal of Luminescence

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“…31 In SrI 2 crystal having close band gap energy the alike emission was also ascribed to self-trapped exciton emission. 3,4 The STE luminescence quenching with Eu 2+ concentration is due to the exciton emission and 4f-5d Eu 2+ absorption spectra overlapping. This fact makes possible a resonant transfer from exciton to Eu 2+ ions.…”

Section: Exciton Emission and Band Gapmentioning

confidence: 99%

“…1 This material has been more extensively studied with optical spectroscopy methods within the past decade. Spectroscopic data measured in ultraviolet and vacuum ultraviolet (VUV) together with Ab Initio calculations provided the information about exciton and band gap energies [2][3][4][5] and is necessary for understanding mechanism of defect formation and their role in energy transfer.…”

Section: Introductionmentioning

confidence: 99%

Optical and structural properties of Eu2+ doped BaBrI and BaClI crystals

Shendrik

Shalaev

Myasnikova

et al. 2017

Journal of Luminescence

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The work is necessitated by search for new materials to detect ionizing radiation.The rare-earth ions doped with ternary alkali earth-halide systems are promising scintillators showing high efficiency and energy resolution. Some aspects of crystal growth and data on the structural and luminescence properties of BaBrI and BaClI doped with low concentrations of Eu 2+ ions are reported. The crystals are grown by the vertical Bridgman method in sealed quartz ampoule. New crystallography data for BaClI single crystal obtained by single crystal X-ray diffraction method are presented in this paper. Emission, excitation and optical absorption spectra as well as luminescence decay kinetics are studied under excitation by X-ray, vacuum ultraviolet and ultraviolet radiation. The energies of the first 4f-5d transition in Eu 2+ and band gap of the crystals have been obtained. We have calculated the electronic band structure of the crystals using density functional theory as implemented in the Ab Initio. Calculated band gap energies are in accord with the experimental estimates. The energy of gaps between the occupied Eu 2+ 4f level and the valence band top are predicted. In addition, positions of lanthanide energy levels in relation to valence band have been constructed using the chemical shift model.Recently the research focus is shifted to the study of mixed halide compounds due to their superior light yield . 6 In a number of barium dihalides BaFI-BaClI-BaBrI-BaBrCl, the scintillation properties have been studied for Eu-doped BaFI, BaBrCl and BaBrI. 7-11 Despite their excellent properties, experimental data on optical absorption and excitation spectra in spectral region of 4f-5d and band to band transitions are scarce because single-crystals doped with high concentrations of Eu 2+ ions (more than 5 mol. %) were used. When measuring high concentration doped samples, the inner filter effects can be observed. These include reabsorption and non uniform excitation throughout the sample. These effects dramatically change the shape of excitation spectrum. Therefore, estimation of the lowest energy of 4f-5d transitions in Eu-doped BaBrI given in 8,10 is not correct. Furthermore, the experimental determination of band gap in these crystals is not possible due to high absorption related to allowed 4f 6 5d 1 → 4f 7 transitions in Eu 2+ ions. At this moment, the energy of band gap of the mixed halide compounds is based on theoretical estimates.We investigate luminescence, electrical and structural properties of undoped BaBrI, BaBrI-0.05 mol.% Eu 2+ and BaClI-0.1 mol.% Eu 2+ crystals. Absorption, excitation and emission spectra, photoluminescence decay time constants, dielectric properties and pulsed height spectra are presented. The vacuum referred binding (VRBE) energy diagram is constructed in conformity with density functional study. It displays the electron binding energy in the ground and excited state levels of all divalent and trivalent lanthanides ions in BaBrI and BaClI crystals. Methodology Growth and Structural Characteriza...

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