The cloud adjacency effect on surface reflectance retrievals for the region of the Russian Federation with coordinates 51–54∘N, 103–109∘E including the southern part of Lake Baikal for the period of 1–23 July 2021 is assessed in this paper. The method is based on the computer program for statistical simulation of radiative transfer in the atmosphere with the stochastic cloud field including a deterministic gap of a given radius. The results of this program are then used in the interpolation formula. Masks of cloudless pixels, for which the cloud adjacency effect (CAE) changes the ground surface reflectance by more than 0.005, are constructed. The analysis of the resulting CAE radii shows that the average radius is 13.7 km for MODIS band 8, 11.2 km for band 3, 8.4 km for band 4, 7.2 km for band 1, and 7 km for band 2. For the considered MODIS images and bands, the pixels with strong CAE make up from 2.8 to 100% of the total number of cloudless pixels. The correlation coefficients between the initial data and the CAE radius suggest that the cloud optical depth, cloud cover index, and ground surface reflectance exert the major influence on the considered images. A simplified approximation equation for the CAE radius as a function of the cloud optical depth, cloud cover index, and surface reflectance is derived. The analysis of the approximation shows that for the considered images, the CAE radius decreases nearly linearly with wavelength for low reflective surfaces. However, for high reflective surfaces, its wavelength dependence is nonlinear.