A microporous luminescent metal–organic framework for highly selective and sensitive sensing of Cu2+ in aqueous solution

Abstract

A luminescent metal-organic framework with small micropores for the enhanced recognition of Cu(2+) exhibits highly sensitive and selective sensing of Cu(2+) in aqueous solution.

Microporous lanthanide metal-organic frameworks

“…In this regard, Chen ' s group reported a microporous Ln-MOF with highly selectivity in the sensing of Cu 2 + in aqueous solution (Xiao et al 2010 ), and Luo and Batten developed a distinct Ln 3 + -doped pathway to target MOF-based luminescent sensing of metal ions (Luo and Batten 2010 ).…”

Syntheses, structures and tunable luminescence of lanthanide metal-organic frameworks based on azole-containing carboxylic acid ligand

“…They are promising as light emitting materials with a wide range of colors provided by inorganic metal centers, organic linkers, guest solvent molecules, as well as metal-organic charge transfer [20][21][22][23][24][25][26][27][28][29][30][31][32][33][34][35][36]. In addition, the emitted color can also be readily modulated by different lanthanide ions and their concentrations, guest species, and excitation wavelengths [37][38][39][40][41].…”

Ratiometric fluorescent detection of biomakers for biological warfare agents with carbon dots chelated europium-based nanoscale coordination polymers

“…The luminescent properties of NCPs can be easily tailored by changing the ligands, lumophore type, metal ion and spatial arrangements for particular applications [8][9][10][11]. Their specific recognition ability together with their luminescent properties have made them been extensively used as fluorescent probes to monitor ions and small molecules, such as Ag + , aromatic amines, explosives, etc [12][13][14][15][16][17]. However, almost all these assays of NCPs-based sensors are carried out in organic solution based on the change of fluorescence intensity, which will deserve serious interference from drift of light resource or detector, the concentration change of probes especially at very low analyte's concentration and environmental factors [18][19][20][21].…”