A multi-residue pesticide determination in fatty food commodities by modified QuEChERS approach and gas chromatography-tandem mass spectrometry

Theurillat, Xanthippe; Dubois, Mathieu; Huertas-Pérez, José F.

doi:10.1016/j.foodchem.2021.129039

Cited by 35 publications

(15 citation statements)

References 27 publications

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“…Improper pretreatment will affect the detection sensitivity, recovery, and sample throughput [7]. The current pretreatment methods for plant-derived oil substrates mainly include dispersion liquid-liquid micro-extraction (DLLME) [8], matrix solid phase dispersion (MSPD) [9,10], low temperature fat precipitation (LTFP) [11], solid phase extraction (SPE) [5], and QuEChERS [12][13][14][15][16]. The QuEChERS method requires fewer reagent consumables and short pretreatment time, so it is accepted by more and more experimenters [17].…”

Section: Introductionmentioning

confidence: 99%

“…The QuEChERS method requires fewer reagent consumables and short pretreatment time, so it is accepted by more and more experimenters [17]. Theurillat et al established the QuEChERS method to determine the residues of various pesticides and verified the method for 176 pesticides in six oily matrices [12]. Rutkowska et al investigated the matrix effect and recovery of four seed samples of cress, fennel, flax, and hemp.…”

Section: Introductionmentioning

confidence: 99%

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QuEChERS Method Combined with Gas- and Liquid-Chromatography High Resolution Mass Spectrometry to Screen and Confirm 237 Pesticides and Metabolites in Cottonseed Hull

Tong

Xie

Huang³

et al. 2022

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Cottonseed hull is a livestock feed with large daily consumption. If pesticide residues exceed the standard, it is easy for them to be introduced into the human body through the food chain, with potential harm to consumer health. A method for multi-residue analysis of 237 pesticides and their metabolites in cottonseed hull was developed by gas-chromatography and liquid-chromatography time-of-flight mass spectrometry (GC-QTOF/MS and LC-QTOF/MS). After being hydrated, a sample was extracted with 1% acetic acid in acetonitrile, then purified in a clean-up tube containing 400 mg MgSO4, 100 mg PSA, and 100 mg C18. The results showed that this method has a significant effect in removing co-extracts from the oily matrix. The screening detection limit (SDL) was in the range of 0.2–20 μg/kg, and the limit of quantification (LOQ) was in the range of 0.2–20 μg/kg. The recovery was verified at the spiked levels of 1-, 2-, and 10-times LOQ (n = 6), and the 237 pesticides were successfully verified. The percentages of pesticides with recovery in the range of 70–120% were 91.6%, 92.8%, and 94.5%, respectively, and the relative standard deviations (RSDs) of all pesticides were less than 20%. This method was successfully applied to the detection of real samples. Finally, this study effectively reduced the matrix effect of cottonseed hull, which provided necessary data support for the analysis of pesticide residues in oil crops.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

QuEChERS Method Combined with Gas- and Liquid-Chromatography High Resolution Mass Spectrometry to Screen and Confirm 237 Pesticides and Metabolites in Cottonseed Hull

Tong

Xie

Huang³

et al. 2022

Separations

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“…There are many methods of detecting heavy metals, antibiotics, pesticides, and toxins, such as gas chromatography-mass spectrometry, 12,13 liquid chromatography-mass spectrometry, [14][15][16][17][18][19][20][21] inductively coupled plasma mass spectrometry, 22 graphite furnace atomic absorption spectrometry, 23 and electrochemical sensors 24,25 . All of these methods can offer accurate and sensitive results for contamination analysis.…”

Section: Introductionmentioning

confidence: 99%

Research progress on photoelectrochemical sensors for contamination analysis in agricultural fields

et al. 2022

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The establishment of rapid and efficient contamination detection methods in agricultural fields is of great significance for safeguarding agricultural production and human health, and for ensuring the healthy development of agricultural industries. As a booming analytical method, photoelectrochemical (PEC) sensors, which combine the advantages of electrochemical analysis and optical analysis, have received increasing research attention. Due to the complete separation of the excitation source (light) and the detection signal (current), the background signal of PEC sensors is greatly decreased, and their sensitivity is high. This review aims to cover the advances in PEC sensors for contamination analysis in agricultural fields over the past five years, including analysis of heavy metals, antibiotics, pesticides, and toxins. The future prospects in this field are also discussed.

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“…The complex nature of aquatic product matrices often dictates the requirement for comprehensive sample cleanup prior to successful data acquisition [23]. Common sample cleanup methods include SPE [24,25], the quick, easy, cheap, effective, rugged and safe (QuEChERS) method [26,27], magnetic solid-phase dispersion combined with liquid-liquid extraction [28], displacement fluorescence polarization immunoassay [29], accelerated solvent extraction [30], and dispersion liquid-liquid microextraction [31]. Among these, SPE provides a large enrichment factor, thereby permitting simultaneous sample cleanup and concentration.…”

Section: Introductionmentioning

confidence: 99%

Application of solid‐phase extraction: High‐resolution mass spectrometry analysis strategy in the characterization and quantification of amide herbicides in aquatic products

et al. 2022

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In this study, we developed a new method combining thin-layer ultrasonic extraction, efficient SPE purification, ultra-performance liquid chromatography separation, and high-resolution mass spectrometry characterization for seven amide herbicides in fishery products. In sample preparation, to rapidly increase the contact area between the fish meat and the extractant, the fish meat was smeared on a glass slide. This process resulted in quickly reaching the extraction equilibrium and relatively high extraction efficiency. In data analysis, a strategy for characterization and qualitative analysis was constructed by analyzing the fragmentation of amide herbicides using product ion scans. Isomeric pretilachlor and butachlor were separated chromatographically, while the coeluting isomers, alachlor and acetochlor, could be separated by differences in the fragmentation of their selected precursor ions. This method overcame the challenge of poor dispersion in the extractant caused by the high viscosity of fish meat, and the challenge of separation and characterization for isomers. Compared with other methods, the extraction efficiency was improved and the amide herbicides in aquatic products was characterized and quantified rapidly and accurately. Moreover, the qualitative information was much greater and provided an additional strategy for analytes identification. This rapid and accurate method will benefit workers involved in monitoring fishery.

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A multi-residue pesticide determination in fatty food commodities by modified QuEChERS approach and gas chromatography-tandem mass spectrometry

Cited by 35 publications

References 27 publications

QuEChERS Method Combined with Gas- and Liquid-Chromatography High Resolution Mass Spectrometry to Screen and Confirm 237 Pesticides and Metabolites in Cottonseed Hull

QuEChERS Method Combined with Gas- and Liquid-Chromatography High Resolution Mass Spectrometry to Screen and Confirm 237 Pesticides and Metabolites in Cottonseed Hull

Research progress on photoelectrochemical sensors for contamination analysis in agricultural fields

Application of solid‐phase extraction: High‐resolution mass spectrometry analysis strategy in the characterization and quantification of amide herbicides in aquatic products

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