This work presents the use of transfer-learning-based algorithms as data reduction strategies for classification of volatile organic compounds (VOCs) using optical emission spectroscopy (OES) of plasmas. The plasma used is generated with a home-made microplasma generation device (MGD) ignited in the mixtures of Ar and VOCs. The spectra are acquired from 10 MGDs. The VOC tested are methanol, ethanol, and isopropanol. VOCs are classified using a convolutional neural network (CNN). In addition, gradient-weighted class activation mapping (Grad-CAM) is used as the explainable artificial intelligent technique. It ensures the model classification is based upon rational plasma physics by considering appropriate wavelengths. The VOC concentrations are then quantified using linear regression and an artificial neural network (ANN). Transfer learning-based algorithms tested are parameter transfer, REPTILE, and self-training. Spectral data from 10 MGDs are grouped into source and target datasets. Ten MGDs are tested individually using a model that was trained on the rest nine MGDs. The three MGDs with the lowest accuracy are chosen as the target dataset, while the other seven MGDs make up the source dataset. The original target dataset has 22500 spectra and is further reduced to 12600, 9000, 1800, 225, and 22 spectra to test the behavior of each algorithm. With 225 spectra used for training, the model trained with the random initial (RI) model shows an accuracy of 0.82. The models trained with parameter transfer and REPTILE have accuracies of 0.98 and 0.95, respectively. Finally, an ANN model is used to quantify the VOC concentration with an R2 value of 0.9996. The results demonstrate the potential using transfer-learning-based algorithms as the data reduction strategies for classification of spectroscopic data.