1998
DOI: 10.1002/(sici)1097-4628(19980411)68:2<173::aid-app1>3.0.co;2-n
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A new homologous series of linear aliphatic unsaturated hydroxypolyesters a polyol soft segments for polyurethanes: Synthesis and characterization

Abstract: Synthesis and characterization of a new series of low molecular weight (MW Å 500-3000) OH-terminated linear aliphatic unsaturated polyesters based on cis-2-butene-1,4-diol and oxalic to sebacic acid were investigated. Direct polycondensation and transesterification methods were used for the syntheses. The latter was recognized to be the preferable method due to its lower reaction temperature and time, lower diol/diacid ratio, absence of decarboxylation, and formation of a product with low polydispersity ( M V … Show more

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Cited by 25 publications
(15 citation statements)
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“…[37] Erythritol is a sugar substitute that is approved by the FDA. [69][70][71][72][73][74][75][76] Due to such a wide spectrum of starting materials, the macromolecular characteristics of the poly(erythritol dicarboxylate) (PErD) are diverse. Erythritol is absorbed by the body and excreted unaltered, implying that normal metabolic pathways continue to be unaffected.…”
Section: Poly(polyol Sebacate)mentioning
confidence: 99%
“…[37] Erythritol is a sugar substitute that is approved by the FDA. [69][70][71][72][73][74][75][76] Due to such a wide spectrum of starting materials, the macromolecular characteristics of the poly(erythritol dicarboxylate) (PErD) are diverse. Erythritol is absorbed by the body and excreted unaltered, implying that normal metabolic pathways continue to be unaffected.…”
Section: Poly(polyol Sebacate)mentioning
confidence: 99%
“…This is seen upon comparing the values for SAl, AAI and SU1; these values are 48.2, 52.0 and 58.7 0 C respectively. It is well known that the spacing between the sites of cross-linking will occasionally reduce the heat generated from the cross-linking reaction [34,35,36]. In addition to that, the longer molecules are slower in motion and in collisions than shorter ones.…”
Section: Determination Of the Curing Exothermsmentioning
confidence: 99%
“…Palmeri oil, vernonia oil, castor oil, cardanol oil and soy oil have been synthesized with multiple functionality, an alternative to replace the petrochemical based polyols [5,6,7]. Badri et.…”
Section: Introductionmentioning
confidence: 99%
“…The utilization of lignocellulosic materials in making composites has received considerable attention, in recent times particularly in thermoplastic composites [5,7,8]. This has been attributed to several advantages offered by lignocelluloses fillers, such as lower density, greater deformability, less abrasiveness to equipment, biodegradability and lower cost [9,10].…”
Section: Introductionmentioning
confidence: 99%