A single-pulse shock
tube study of the pyrolysis of two different
concentrations of Chinese RP-3 jet fuel at 5 bar in the temperature
range of 900–1800 K has been performed in this work. Major
intermediates are obtained and quantified using gas chromatography
analysis. A flame-ionization detector and a thermal conductivity detector
are used for species identification and quantification. Ethylene is
the most abundant product in the pyrolysis process. Other important
intermediates such as methane, ethane, propyne, acetylene, butene,
and benzene are also identified and quantified. Kinetic modeling is
performed using several detailed, semidetailed, and lumped mechanisms.
It is found that the predictions for the major species such as ethylene,
propene, and methane are acceptable. However, current kinetic mechanisms
still need refinement for some important species. Different kinetic
mechanisms exhibit very different performance in the prediction of
certain species during the pyrolysis process. The rate of production
(ROP) is carried out to compare the differences among these mechanisms
and to identify major reaction pathways to the formation and consumption
of the important species, and the results indicate that further studies
on the thermal decomposition of 1,3-butadiene are needed to optimize
kinetic models. The experimental data are expected to contribute to
a database for the validation of mechanisms under pyrolytic conditions
for RP-3 jet fuel and should also be valuable to a better understanding
of the combustion behavior of RP-3 jet fuel.