A new, quick, highly sensitive ultramicro-analysis method for the identification of fructose removed from fructofuranosyl-containing gluco-oligosaccharides by ESI-CID-MS/MS

Zhang, Hongtao; Zhu, Li; Zhang, Shuang; Zhan, Xi; Lin, Chi-Chung

doi:10.1016/j.carres.2014.08.013

Cited by 4 publications

(2 citation statements)

References 21 publications

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“…Several papers, and a review (Bergman, Shevchenko, & Bergquist, ) (123 cited references) have appeared, in addition to the one cited above, (Zhang et al, ) with methods for observing ions from the low mass region of the spectrum, a region usually populated with abundant ions from the matrix.…”

Section: Matricesmentioning

confidence: 99%

“…To couple carbohydrates to arrays, it is necessary to have a free or activated reducing terminus. Fructofuranosyl‐containing gluco‐oligosaccharides do not have such a terminus but the fructose can be removed by incubation with 0.5 M TFA (Zhang et al, ) with the products identified by MALDI‐TOF MS. Beloqui et al () have constructed arrays with activated bidentate lipids embedded into a hydrophobic layer which was printed onto an indium‐tin oxide surface. Amino‐functionalized N ‐glycans were then printed on to the activated surface to produce arrays with improved spot morphology and homogeneity and which avoided solubility problems and the strict incubation requirements associated with printing glycolipids or fluorous‐tagged glycans.…”

Section: Glycan Arraysmentioning

confidence: 99%

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Analysis of carbohydrates and glycoconjugates by matrix‐assisted laser desorption/ionization mass spectrometry: An update for 2013–2014

Harvey

2018

Mass Spectrometry Reviews

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This review is the eighth update of the original article published in 1999 on the application of Matrix-assisted laser desorption/ionization mass spectrometry (MALDI) mass spectrometry to the analysis of carbohydrates and glycoconjugates and brings coverage of the literature to the end of 2014. Topics covered in the first part of the review include general aspects such as theory of the MALDI process, matrices, derivatization, MALDI imaging, fragmentation, and arrays. The second part of the review is devoted to applications to various structural types such as oligo- and poly- saccharides, glycoproteins, glycolipids, glycosides, and biopharmaceuticals. Much of this material is presented in tabular form. The third part of the review covers medical and industrial applications of the technique, studies of enzyme reactions, and applications to chemical synthesis. © 2018 Wiley Periodicals, Inc. Mass Spec Rev 37:353-491, 2018.

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Section: Matricesmentioning

confidence: 99%

Section: Glycan Arraysmentioning

confidence: 99%

Analysis of carbohydrates and glycoconjugates by matrix‐assisted laser desorption/ionization mass spectrometry: An update for 2013–2014

Harvey

2018

Mass Spectrometry Reviews

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Functional properties, structural studies and chemo-enzymatic synthesis of oligosaccharides

Zhao

Liu

et al. 2017

Trends in Food Science & Technology

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Functional properties, structural studies and chemoenzymatic synthesis of oligosaccharides http://researchonline.ljmu.ac.uk/6683/ Article LJMU has developed LJMU Research Online for users to access the research output of the University more effectively. Copyright © and Moral Rights for the papers on this site are retained by the individual authors and/or other copyright owners. Users may download and/or print one copy of any article(s) in LJMU Research Online to facilitate their private study or for non-commercial research. You may not engage in further distribution of the material or use it for any profit-making activities or any commercial gain.The version presented here may differ from the published version or from the version of the record. Please see the repository URL above for details on accessing the published version and note that access may require a subscription. The authors declare that there is no conflict of interest regarding the publication of this article. 17Abstract: Oligosaccharides offer beneficial effects on immune system and gut health, such 18 as anticancer activity, immunomodulatory activity, and complement activation.

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Bioactive polysaccharides and oligosaccharides from garlic (Allium sativum L.): Production, physicochemical and biological properties, and structure–function relationships

Qiu

Qiao

Zhang

et al. 2022

Comp Rev Food Sci Food Safe

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Garlic is a common food, and many of its biological functions are attributed to its components including functional carbohydrates. Garlic polysaccharides and oligosaccharides as main components are understudied but have future value due to the growing demand for bioactive polysaccharides/oligosaccharides from natural sources. Garlic polysaccharides have molecular weights of 1 × 103 to 2 × 106 Da, containing small amounts of pectins and fructooligosaccharides and large amounts of inulin‐type fructans ((2→1)‐linked β‐d‐Fruf backbones alone or with attached (2→6)‐linked β‐d‐Fruf branched chains). This article provides a detailed review of research progress and identifies knowledge gaps in extraction, production, composition, molecular characteristics, structural features, physicochemical properties, bioactivities, and structure–function relationships of garlic polysaccharides/oligosaccharides. Whether the extraction processes, synthesis approaches, and modification methods established for other non‐garlic polysaccharides are also effective for garlic polysaccharides/oligosaccharides (to preserve their desired molecular structures and bioactivities) requires verification. The metabolic processes of ingested garlic polysaccharides/oligosaccharides (as food ingredients/dietary supplements), their modes of action in healthy humans or populations with chronic conditions, and molecular/chain organization–bioactivity relationships remain unclear. Future research directions related to garlic polysaccharides/oligosaccharides are discussed.

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A new, quick, highly sensitive ultramicro-analysis method for the identification of fructose removed from fructofuranosyl-containing gluco-oligosaccharides by ESI-CID-MS/MS

Cited by 4 publications

References 21 publications

Analysis of carbohydrates and glycoconjugates by matrix‐assisted laser desorption/ionization mass spectrometry: An update for 2013–2014

Analysis of carbohydrates and glycoconjugates by matrix‐assisted laser desorption/ionization mass spectrometry: An update for 2013–2014

Functional properties, structural studies and chemo-enzymatic synthesis of oligosaccharides

Bioactive polysaccharides and oligosaccharides from garlic (Allium sativum L.): Production, physicochemical and biological properties, and structure–function relationships

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