With environmental issues becoming increasingly important worldwide, plenty of enterprises have applied the green supply chain management (GSCM) mode to achieve economic benefits while ensuring environmental sustainable development. As an important part of GSCM, green supplier selection has been researched in many literatures, which is regarded as a multiple criteria group decision making (MCGDM) problem. However, these existing approaches present several shortcomings, including determining the weights of decision makers subjectively, ignoring the consensus level of decision makers, and that the complexity and uncertainty of evaluation information cannot be adequately expressed. To overcome these drawbacks, a new method for green supplier selection based on the q-rung orthopair fuzzy set is proposed, in which the evaluation information of decision makers is represented by the q-rung orthopair fuzzy numbers. Combined with an iteration-based consensus model and the q-rung orthopair fuzzy power weighted average (q-ROFPWA) operator, an evaluation matrix that is accepted by decision makers or an enterprise is obtained. Then, a comprehensive weighting method can be developed to compute the weights of criteria, which is composed of the subjective weighting method and a deviation maximization model. Finally, the TODIM (TOmada de Decisao Interativa e Multicritevio) method, based on the prospect theory, can be extended into the q-rung orthopair fuzzy environment to obtain the ranking result. A numerical example of green supplier selection in an electric automobile company was implemented to illustrate the practicability and advantages of the proposed approach.