A new simple sensitive differential pulse polarographic method for the determination of acrylamide in aqueous solution

Niaz, Abdul; Sirajuddin, Sirajuddin; Shah, Afzal; Bhanger, Muhammad Iqbal; Saeed, Munawar; Jamali, Mohammad Khan; Arain, Mohammad Balal

doi:10.1016/j.talanta.2007.10.010

Cited by 12 publications

(8 citation statements)

References 10 publications

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“…The mechanism of reduction of AA in neutral methanolic and aqueous solutions has been described previously (Vajda 1967;Niaz 2008).…”

Section: Resultsmentioning

confidence: 99%

“…Acrylamide reduces at the Hg electrode in a negative potential, which can be overlaid by a reduction wave of alkali metals. A differential pulse polarographic method for the determination of AA in aqueous solutions using LiCl as supporting electrolyte with a well-defined peak for AA at À1.84 V has been reported (Niaz 2008). In this research, trace amounts of AA in the presence of cobalt(II) ions have been determined by square-wave (SW) voltammetry.…”

Section: Introductionmentioning

confidence: 99%

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Catalytic Square-Wave Voltammetric Determination of Acrylamide in Potato Chips

Zargar

Sahraie

Khoshnam³

2009

Analytical Letters

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Square-wave voltammetry is a fast technique used for determination of trace amounts of acrylamide. When cobalt(II) ions were added to the acrylamide solution, a catalytic peak at about À1.35 V vs. Ag=AgCl was observed, which was proportional to acrylamide concentration. The calibration curve showed good linearity in the range of 200-800 ng mL À1 of acrylamide with a regression coefficient of 0.9989. The limit of detection of the method was 3.52 ng mL À1 , and the relative standard deviations for concentrations of 300 ng mL À1 and 700 ng mL À1 were 99.8% Â 10 À2 and 79.7% Â 10 À2 , respectively.

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“…The mechanism of reduction of AA in neutral methanolic and aqueous solutions has been described previously (Vajda 1967;Niaz 2008).…”

Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Catalytic Square-Wave Voltammetric Determination of Acrylamide in Potato Chips

Zargar

Sahraie

Khoshnam³

2009

Analytical Letters

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“…Another detection principle is based on the catalysis of the reduction of AA with the assistance of electrolytes, such as LiCl and cobalt(Ⅱ) ions (Niaz et al, 2008;Zargar, Sahraie, & Khoshnam, 2009). Specifically, AA was reduced with the catalysis of the Co ion accompanied by electron transfer and finally changes in current for signal readout (Zargar et al, 2009).…”

Section: Electrochemical Biosensing Methodsmentioning

confidence: 99%

Rapid methods for detecting acrylamide in thermally processed foods: A review

et al. 2015

Food Control

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“…The benefits of electrochemical methods are relatively inexpensive, high sensitivity, high selectivity, rapid response, easy construction, easy handling, repeatability, and reproducibility can be considered as an excellent choice for detection of AA. Differential pulse polarography, [ 21 ] square‐wave voltammetry, [22 ] and LC coupled with pulsed electrochemical detection [ 23 ] were used for the determination of AA. Bioanalytical approaches, such as immunoenzymatic experiments and biosensors, which have been shown to be sufficiently sensitive and selective, are another useful tool for AA determination.…”

Section: Introductionmentioning

confidence: 99%

A molecular biomimetic sensor of tris(2‐benzimidazolylmethyl)amine‐based iron(III) complex for acrylamide detection: Electrochemical study and DFT calculations

Mersal

Hessien

Jouaid

et al. 2021

J Chinese Chemical Soc

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A new biomimetic sensor (BS) has been prepared by modifying the carbon paste electrode (CPE) based on [Fe(NTB)Cl2]Cl·EtOH (FeC) {NTB = tris(2‐benzimidazolylmethyl)amine} for the electrochemical detection of acrylamide (AA). The development of the reported BS was focused on the creation of an AA with α‐NH2 group of N‐terminal valine of hemoglobin (HG), which reduces the peak current of HG‐Fe+3 reduction. The fabricated BS was characterized by scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV), as well as square wave voltammetry (SWV) for studying the electrochemical properties of AA on its surface. Under optimized conditions, the BS was applied for the direct determination of AA in two linear concentration ranges: 1.0 × 10−6 and 1.0 × 10−4 M. The first linear was observed from 1.0 × 10−6 to 1 × 10−5 M with a limit of detection (LOD) of 1.465 × 10−7 M, while the second linear part was detected from 1.0 × 10−5 to 1 × 10−4 M with LOD of 5.67 × 10−6 M. Finally, the constructed BS was successfully applied for the evaluation of AA in various potato chips, and the results were comparable to those obtained from other electrochemical methods. The density functional theory (DFT) could successfully explain the recognition process of acrylamide, that is, the hydroamination of the alkene group of acrylamide by imidazole moiety of the iron complex.

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A new simple sensitive differential pulse polarographic method for the determination of acrylamide in aqueous solution

Cited by 12 publications

References 10 publications

Catalytic Square-Wave Voltammetric Determination of Acrylamide in Potato Chips

Catalytic Square-Wave Voltammetric Determination of Acrylamide in Potato Chips

Rapid methods for detecting acrylamide in thermally processed foods: A review

A molecular biomimetic sensor of tris(2‐benzimidazolylmethyl)amine‐based iron(III) complex for acrylamide detection: Electrochemical study and DFT calculations

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