Acta Cryst E
 2018
DOI: 10.1107/s2056989018010939
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A new structural model for NiFe hydrogenases: an unsaturated analogue of a classic hydrogenase model leads to more enzyme-like Ni—Fe distance and interplanar fold

Daniel J. Harrison
1
,
Alan J. Lough
2
,
Ulrich Fekl
3

Abstract: The new structural NiFe hydrogenase model [Ni(L′)FeCp*(CO)][PF6] [L′ = S—C(Me)=C(Me)—S—(CH2)3—S—C(Me)=C(Me)—S] is reported.

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