A Ni/perovskite catalyst with low metal content for CO2 reforming of methane

Jin, Rongrong; An, Li; Bai, Xiaoli; Wang, Zhou‐jun

doi:10.1016/j.catcom.2022.106419

Cited by 17 publications

(8 citation statements)

References 24 publications

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“…3 Results and discussion However, the diffraction peaks of NiO and In 2 O 3 could not be observed in the XRD pattern, which may be due to the low content of NiO and In 2 O 3 in the catalyst. 30,31 As shown in Fig. 1B, the N 2 adsorption-desorption isotherms for the support and catalysts were closest in shape to a type IV adsorption isotherm, indicating the formation of mesoporous structures, which were related to the interactions between the molecules in the solidified state.…”

Section: Drm Reactionmentioning

confidence: 76%

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Coke-resistant Ni-based bimetallic catalysts for the dry reforming of methane: effects of indium on the Ni/Al₂O₃catalyst

Wang

Qin

et al. 2022

Catal. Sci. Technol.

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Section: Drm Reactionmentioning

confidence: 76%

“…7 However, the diffraction peaks of NiO and In 2 O 3 could not be observed in the XRD pattern, which may be due to the low content of NiO and In 2 O 3 in the catalyst. 30,31…”

Section: Resultsmentioning

confidence: 99%

Coke-resistant Ni-based bimetallic catalysts for the dry reforming of methane: effects of indium on the Ni/Al₂O₃catalyst

Wang

Qin

et al. 2022

Catal. Sci. Technol.

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“…Deactivation studies of impregnating Ni in different amounts on Ca-doped La-containing aluminate perovskites La 0.9 Ca 0.1 AlO 2.95 yielded different deactivation mechanisms as a function of Ni particle size. Small Ni particles tended to deactivate via metal particle sintering, but for larger ones, deactivation by carbon deposition becomes more important [43]. A strongly reduced sintering of exsolved metallic Ni particles has been observed for LaNi x A l−x O 3 perovskites due to strong interaction of Ni with the perovskite [44].…”

Section: Aluminatesmentioning

confidence: 99%

Metal–Perovskite Interfacial Engineering to Boost Activity in Heterogeneous Catalysis

Malleier,

Penner

2024

Surfaces

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In this review, we have assessed the possibility of metal–perovskite interfacial engineering to enhance the catalytic activity and selectivity in a range of heterogeneous catalytic reactions. We embarked on a literature screening of different perovskite material classes and reactions to show the versatility of the perovskite structures to induce the formation of such hetero-interfaces and the widespread nature of the phenomenon in catalytic research. There is almost no limitation on the chemical composition of the used perovskites and the nature of the catalyzed reaction, be it under reduction or oxidation conditions. We attempted to classify the perovskite materials, discuss the different strategies leading to the hetero-interfaces, and detail the synergistic action of the components of the respective interfaces. We also provide a critical assessment of the large body of data that is available in terms of a knowledge-based approach to the comparison of differently prepared interfaces with varying interfacial extent to gain a deeper understanding of the bi-functional operation of the interfaces and the urgent necessity to study and characterize such interfaces under realistic operation conditions.

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“…Perovskites are used in various reactions, − especially for oxidation reactions such as the oxidation of nitrogen oxide ,, and carbon monoxide, , because of their excellent thermal stability, electronic structure, ionic conductivity, electron mobility, and redox behavior. Consequently, perovskites are expected to display excellent performance in NO x production.…”

Section: Introductionmentioning

confidence: 99%

Coupling of LaFeO₃–Plasma Catalysis and Cu⁺/Cu⁰ Electrocatalysis for Direct Ammonia Synthesis from Air

Cui

Yang

Dai

et al. 2022

Ind. Eng. Chem. Res.

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Ammonia (NH3) is an essential commodity manufactured by the chemical industry. However, it is still mainly synthesized via the traditional Haber–Bosch process, which is energy consuming and produces large amounts of CO2. As one of the most promising alternatives, the electrochemical reduction of nitrogen (N2) under mild reaction conditions exhibits only low efficiency for NH3 synthesis because of the low water solubility of N2 and the high energy of the triple bond in molecular N2. Here, we use an N2 fixation strategy of “oxidation–reduction” based on a coupled plasma catalysis and electrocatalytic system. First, a perovskite LaFeO3 catalyst is used in a nonthermal plasma to oxidize N2 to nitrate/nitrite (NO x –), which quickly dissolves in water for activation in the next step. The theoretical calculations indicate that the LaFeO3 with rich surface-reactive oxygen species has better activity and stability in the reaction than poor surface-reactive oxygen species, thereby enhancing the increase of NO x – production. Then NO x – is electrochemically reduced to NH3 using a Cu+/Cu0 catalyst with considerable activity (3.0 mg h–1 cm–2) and high faradaic efficiency (83.2%). The process only requires air and water as reactants. This strategy could provide a new and efficient pathway for NH3 synthesis directly from the air.

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A Ni/perovskite catalyst with low metal content for CO2 reforming of methane

Cited by 17 publications

References 24 publications

Coke-resistant Ni-based bimetallic catalysts for the dry reforming of methane: effects of indium on the Ni/Al₂O₃catalyst

Coke-resistant Ni-based bimetallic catalysts for the dry reforming of methane: effects of indium on the Ni/Al₂O₃catalyst

Metal–Perovskite Interfacial Engineering to Boost Activity in Heterogeneous Catalysis

Coupling of LaFeO₃–Plasma Catalysis and Cu⁺/Cu⁰ Electrocatalysis for Direct Ammonia Synthesis from Air

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A Ni/perovskite catalyst with low metal content for CO2 reforming of methane

Cited by 17 publications

References 24 publications

Coke-resistant Ni-based bimetallic catalysts for the dry reforming of methane: effects of indium on the Ni/Al2O3catalyst

Coke-resistant Ni-based bimetallic catalysts for the dry reforming of methane: effects of indium on the Ni/Al2O3catalyst

Metal–Perovskite Interfacial Engineering to Boost Activity in Heterogeneous Catalysis

Coupling of LaFeO3–Plasma Catalysis and Cu+/Cu0 Electrocatalysis for Direct Ammonia Synthesis from Air

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Product

Resources

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Coke-resistant Ni-based bimetallic catalysts for the dry reforming of methane: effects of indium on the Ni/Al₂O₃catalyst

Coke-resistant Ni-based bimetallic catalysts for the dry reforming of methane: effects of indium on the Ni/Al₂O₃catalyst

Coupling of LaFeO₃–Plasma Catalysis and Cu⁺/Cu⁰ Electrocatalysis for Direct Ammonia Synthesis from Air