A nickel and cobalt bimetal organic framework with high capacity as an anode material for lithium-ion batteries

Abstract

The Ni–Co-BTC anode shows excellent electrochemical performance, which could be ascribed to the intercalation/deintercalation mechanism and the synergistic effect of two cations.

Water-Driven Structural Transformation in Cobalt Trimesate Metal-Organic Frameworks

“…This material showed also a very high thermal stability, reported to be up 450 • C [47]. On the other hand, a mixed nickel and cobalt 1,3,5-benzenetricarboxylate (Ni-Co-BTC) was proposed as anode material for lithium-ion batteries [49].…”

One step synthesis of a bimetallic (Ni and Co) metal–organic framework for the efficient electrocatalytic oxidation of water and hydrazine

“…As reported in the literature, free TMA shows characteristic bands at 3088, 1721, and 536 cm −1 which correspond to –OH stretching, –CO stretching, and –CO bending vibrations, which are not present in the synthesized MOFs. 28 The strong bands at 1615 and 1368 cm −1 are attributed to –COO asymmetric and symmetric stretching vibrations, respectively, which indicates that the carboxylic group of TMA has coordinated with the metal via a bidentate mode and comprises a polymeric structure. 29,30 The shift in peak from 1721 to 1615 cm −1 indicates that the carboxylic group of TMA is deprotonated and binds with metal, which can be further proved by the presence of a metal-ligand peak at 720 cm −1 .…”

Highly Synergistic Co3+ and Pyridinic‐N‐Rich Bifunctional Electrocatalyst for Ultra‐Low Energy‐Driven Effective Hydrogen Production and Urea Oxidation

“…Two stretching band vibrations are observed at 1375 and 1625 cm -1 , which are, respectively, assigned to the symmetric and asymmetric vibrations of the carboxylic acid functional groups in the BTC molecule. [72] The Co 3 O 4 @NC/NiO/NF sample shows two stretching vibrations at 484 and 616 cm -1 , which strongly suggests the presence of metal oxides such as Ni-O and Co-O. [73] XPS was conducted to investigate the surface chemistry, elemental composition, and electronic oxidation states of the developed materials.…”