A novel 12-molybdovanadate nanocluster: Synthesis, structure investigation and its application as an efficient heterogeneous sulfoxidation catalyst

Binuclear copper complex as a new dual‐use catalyst for cycloaddition and coupling reactions: Synthesis, characterization, and application

“…Transition metal catalysis has been widely employed to assist in intricate chemical conversions, ultimately yielding products of high value. [1][2][3][4][5][6][7][8][9][10] Among these, for several decades, transition metal complexes have been of special attention because of their catalytic abilities. [11][12][13][14] Recently, there has been a focus on developing new copper complexes with various ligands containing oxygen and nitrogen donors and studying their catalytic activity, especially in environmentally friendly processes.…”

“…[15][16][17] Binuclear complexes are experiencing a resurgence of interest because of the potential of bimetallic cooperativity. Binuclear catalysis operates on the idea that sequential or cooperative participation of two metal components could result in increased reaction rates, improve selectivity, enhance the catalytic efficiency, and even introduce novel reaction pathways in organic reactions including C-C bond-forming, A 3 -coupling, azide-alkyne cycloaddition, and … reactions compared with a single metal ion. [18][19][20] Therefore, our focus has been on the development of catalysts derived from bimetallic complexes.…”

“…Transition metal catalysis has been widely employed to assist in intricate chemical conversions, ultimately yielding products of high value 1–10 . Among these, for several decades, transition metal complexes have been of special attention because of their catalytic abilities 11–14 .…”

“…1,2,3-Triazole, A 3 -coupling reaction, binuclear copper (II) complex, click reaction, propargylamine…”

Organic/Inorganic Species Synergistically Supported Unprecedented Vanadomolybdates

“…Vanadomolybdates (VMos), as one of the important branches of POM chemistry, have attracted extensive attention due to their diverse structures and multi-functions in the fields of electrochemistry, magnetism, and catalysis [ 15 , 16 , 17 ]. Compared with other POMs, VMos have a stronger ability to gain or lose electrons, and therefore possess a higher activity, resulting in their excellent properties [ 18 , 19 ]. On the other hand, the structures of VMos have relatively low stability, especially those of lacunary species, which need additional components to support their architectures.…”