“…Field gas ionization system is capable of ionizing the gas molecules by loading a low voltage on the electrodes and is favorable for many potential applications, for example, sensors, , environmental remediation, spectrometry, − and biomedicine . Among them, ionization gas sensors have attracted extensive interest for their advantages like high selectivity and fast response/recovery. , Ionization gas sensing is substantially based on the separation of the positive and negative charges of a gas molecule. , By ionizing the target gas, a specific current–voltage characteristic can be generated as the “fingerprint” of the gas component. , The main disadvantages of traditional bulky ionization gas sensors, for example, high power consumption and risky high operation voltage, hinder their practical application. − Therefore, one-dimensional nanomaterials with ultrasharp tips, for example, carbon nanotubes, as well as ZnO, Si, or CuO nanowires (NWs), − are equipped onto the traditional macroscopic electrodes in order to lower both the operation voltage and the current. Then, intensive studies of decorating the thin film or nanoparticles have been conducted on these nanoelectrodes to further decrease the gas ionization voltages. − However, in contrast to these approaches of additional manufacturing, the study of structural evolution of these microscopic electrodes themselves during the gas ionization is still challenging, and it is worthwhile devoting effort to it, which is strongly associated with the sensing properties of current–voltage ( I – V ) characteristics, repeatability, and stability …”