2019
DOI: 10.1002/zaac.201800476
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A Novel Niobium Cluster Aqua Ion with Capping μ4‐Se Ligand

Abstract: The aqueous solution chemistry of niobium is underexplored, and well characterized aqua complexes are scarce. In this contribution, a new niobium aqua complex was obtained by treatment of Zn‐reduced ethanolic solution of NbCl5 with HCl in the presence of a selenide source (ZnSe). This is the first example of selenium containing aqua complex of niobium. The yellow‐green aqua complex was isolated by cation‐exchange chromatography and transformed into corresponding isothiocyanate complex by ligand exchange, which… Show more

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