A novel ternary mixed matrix membrane containing glycerol-modified poly(ether-block-amide) (Pebax 1657)/copper nanoparticles for CO2 separation

Sanaeepur, Hamidreza; Ahmadi, Reyhane; Amooghin, Abtin Ebadi; Ghanbari, Davood

doi:10.1016/j.memsci.2018.12.012

Cited by 98 publications

(44 citation statements)

References 60 publications

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“…These membranes are also known as mixed matrix membranes (MMMs) . A higher permeability and/or selectivity can be reached by employing MMMs . In other words, these types of membranes present good characteristics of polymeric membrane for various gas separation processes .…”

Section: Introductionsupporting

confidence: 88%

“…In other words, these types of membranes present good characteristics of polymeric membrane for various gas separation processes . Some MMMs applications included air separation (O 2 /N 2 ), CO 2 separation (CO 2 /CH 4 , CO 2 /N 2 , and CO 2 /flue gas), hydrogen separation (H 2 /CH 4 ), and other gaseous components such as propylene/propane separation . On the other hand, modeling of permeation behavior in MMMs can play an effective role in the progressive development of MMMs for separation processes.…”

Section: Introductionmentioning

confidence: 99%

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A new permeation model in porous filler–based mixed matrix membranes for CO₂ separation

2019

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In this paper, a novel comprehensive permeation model for mixed matrix membranes (MMMs) is introduced. This model shows the importance of understanding and developing a more reliable model for the permeation behavior of MMMs containing porous filler nanoparticles. A new method is established to provide a more precise/large‐scale three‐dimensional MMMs geometry. The required number of spherical porous fillers in random/nonuniform positions in the polymer matrix is calculated. Interfacial equilibrium constant (K) at the polymer/filler interfaces was adjusted as the concentration ratio of the diffusing penetrants (C2 and C1) at the interface, respectively. In this case, the K values are changed by varying the intended gaseous concentration due to their permeation through the MMM. Hence, its effect on penetrants effective diffusion coefficient was examined. Then, the obtained results were evaluated with similar experimental data, which showed much consistency. Therefore, the accurate calculation method for MMMs permeability was governed for the entire range of the operating pressures in MMMs. The results showed that the permeability of MMMs increases with increasing filler particle size. On the other hand, variations that occur in the MMM permeability at various particle size were much more distinct at higher loadings. Moreover, some well‐known analytical permeation models were used to compare and validate the model's permeability results. It can be concluded that this model provides a method for more precise and realistic design of MMMs as well as to better construe the large number of related experimental data. © 2019 Society of Chemical Industry and John Wiley & Sons, Ltd.

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Section: Introductionsupporting

confidence: 88%

Section: Introductionmentioning

confidence: 99%

A new permeation model in porous filler–based mixed matrix membranes for CO₂ separation

2019

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“…As the zeolite content increases from 10% to 40 wt %, the peak intensity of 24° decreases significantly along with the shape turning broad. This is attributed to the rupture of hydrogen bonding between the amide chains in PA segments, resulting in the reduced crystallinity in MMMs . Oppositely, the characteristic peak intensity of NaY increases at the same time.…”

Section: Resultsmentioning

confidence: 99%

Preparation and characterization of CO₂‐selective Pebax/NaY mixed matrix membranes

Zheng

Zhang

et al. 2019

J of Applied Polymer Sci

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CO 2 -selective Pebax/NaY mixed matrix membranes (MMMs) were prepared by incorporating NaY zeolite into Pebax matrix. The morphology, chemical groups, thermal stability, and microstructure of the MMMs were investigated by scanning electron microscope, Fourier transform infrared spectroscopy, thermogravimetric analysis, and X-ray diffraction, respectively. The effects of zeolite loading amount, permeation temperature and pressure on the CO 2 /N 2 separation performance of the resultant membranes were studied. The as-prepared MMMs are much superior to the pristine Pebax membranes in terms of permeability and selectivity. The CO 2 permeability and CO 2 /N 2 selectivity can respectively reach to 131.8 Barrer and 130.8 for MMMs made by the starting materials containing 40 wt % NaY.

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“…The success of an MMM largely depends on the type of polymer matrix and inorganic filler as well as the relationship between both phases [74]. The presence of filler particles in polymer matrix could modify the membrane properties and alter the morphologies of the membrane.…”

Section: Gas Permeation Mechanism Through Mixed Matrix Membrane (Mmm)mentioning

confidence: 99%

Potential of adsorbents from agricultural wastes as alternative fillers in mixed matrix membrane for gas separation: A review

Ghazali

Rahman

Samah

2020

Green Processing and Synthesis

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AbstractMixed matrix membrane (MMM), formed by dispersing fillers in polymer matrix, has attracted researchers’ attention due to its outstanding performance compared to polymeric membrane. However, its widespread use is limited due to high cost of the commercial filler which leads to the studies on alternative low-cost fillers. Recent works have focused on utilizing agricultural wastes as potential fillers in fabricating MMM. A membrane with good permeability and selectivity was able to be prepared at low cost. The objective of this review article is to compile all the available information on the potential agricultural wastes as fillers in fabricating MMM for gas separation application. The gas permeation mechanisms through polymeric and MMM as well as the chemical and physical properties of the agricultural waste fillers were also reviewed. Additionally, the economic study and future direction of MMM development especially in gas separation field were discussed.

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A novel ternary mixed matrix membrane containing glycerol-modified poly(ether-block-amide) (Pebax 1657)/copper nanoparticles for CO2 separation

Cited by 98 publications

References 60 publications

A new permeation model in porous filler–based mixed matrix membranes for CO₂ separation

A new permeation model in porous filler–based mixed matrix membranes for CO₂ separation

Preparation and characterization of CO₂‐selective Pebax/NaY mixed matrix membranes

Potential of adsorbents from agricultural wastes as alternative fillers in mixed matrix membrane for gas separation: A review

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A novel ternary mixed matrix membrane containing glycerol-modified poly(ether-block-amide) (Pebax 1657)/copper nanoparticles for CO2 separation

Cited by 98 publications

References 60 publications

A new permeation model in porous filler–based mixed matrix membranes for CO2 separation

A new permeation model in porous filler–based mixed matrix membranes for CO2 separation

Preparation and characterization of CO2‐selective Pebax/NaY mixed matrix membranes

Potential of adsorbents from agricultural wastes as alternative fillers in mixed matrix membrane for gas separation: A review

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A new permeation model in porous filler–based mixed matrix membranes for CO₂ separation

A new permeation model in porous filler–based mixed matrix membranes for CO₂ separation

Preparation and characterization of CO₂‐selective Pebax/NaY mixed matrix membranes