A novel thermophotocatalyst of mixed-phase cerium oxide (CeO2/Ce2O3) homocomposite nanostructure: Role of interface and oxygen vacancies

Verma, Ranjana; Samdarshi, S.K.; Sreedhar, B.; Paul, Samrat; Choudhury, Biswajit

doi:10.1016/j.solmat.2015.06.027

Cited by 134 publications

(59 citation statements)

References 38 publications

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“…[46] Then, the electric conductivity of lattice oxygen can be increased as the temperature is raised, which causes more holes to be transferred to the surface, thereby increasing the activity of the process. [25] In particular, designed CeO 2 -Ce 2 O 3 composites showedactivity under both Vis and IR irradiation. [25] In particular, designed CeO 2 -Ce 2 O 3 composites showedactivity under both Vis and IR irradiation.…”

Section: Water Treatmentmentioning

confidence: 97%

“…[25] In particular, designed CeO 2 -Ce 2 O 3 composites showedactivity under both Vis and IR irradiation. [25] Finally,s omes tudies in which Er and/orY rc omponents induce thermo-photocatalytic processes under Vis and IR excitation can be mentioned. [25] Finally,s omes tudies in which Er and/orY rc omponents induce thermo-photocatalytic processes under Vis and IR excitation can be mentioned.…”

Section: Water Treatmentmentioning

confidence: 97%

“…[20,21] Figure 2B presents as chematic view of the NIR to UV conversion process in YF 3 ,Y b 3 + ,Tm 3 + /TiO 2 core-shell nanoparticles.T hisk ind of materiale mits UV light after absorbing NIR light, and then the UV light excites TiO 2 to generate strongly oxidative holes (h + )a nd reductive electrons (e À ). [24,25] Figure 2D schematically shows the density of states before and after vacuum annealing of the CeO 2 -Ce 2 O 3 sample. [21] 3.…”

Section: Current Strategiest Od Evelop Thermo-photocatalytic Systemsmentioning

confidence: 99%

“…[21] 3. [25] When the energy is released in the form of photons, it causes local heating of the lattice, which establishes at emperature distribution depending on the optical absorption and bulk/surface recombination characteristics. [22,23] Oxides, sulfides, and, particularly,m etal-based materials are used in this context.…”

Section: Current Strategiest Od Evelop Thermo-photocatalytic Systemsmentioning

confidence: 99%

“…Reprinted with permission from Ref. [25].C opyright2 015 Elsevier. B) Mechanism of NIR-activated photocatalysis (ET:energyt ransfer).…”

Section: General Commentsmentioning

confidence: 99%

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Thermo‐Photocatalysis: Environmental and Energy Applications

et al. 2019

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Catalysis is an integral part of a majority of chemical operations focused on the generation of value‐added chemicals or fuels. Similarly, the extensive use of fossil‐derived fuels and chemicals has led to deterioration of the environment. Catalysis currently plays a key role in mitigating such effects. Thermal catalysis and photocatalysis are two well‐known catalytic approaches that were applied in both energy and environmental fields. Thermo‐photocatalysis can be understood as a synergistic effect of the two catalytic processes with key importance in the use of solar energy as thermal and light source. This Review provides an update on relevant contributions about thermo‐photocatalytic systems for environmental and energy applications. The reported activity data are compared with the conventional photocatalytic approach and the base of the photothermal effect is analyzed. Some of the systems based on the positive aspects of thermo‐ and photocatalysis could be the answer to the energy and environmental crisis when taking into account the outstanding results with regard to chemical efficiency and energy saving.

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Section: Water Treatmentmentioning

confidence: 97%

Section: Water Treatmentmentioning

confidence: 97%

Section: Current Strategiest Od Evelop Thermo-photocatalytic Systemsmentioning

confidence: 99%

Section: Current Strategiest Od Evelop Thermo-photocatalytic Systemsmentioning

confidence: 99%

“…Reprinted with permission from Ref. [25].C opyright2 015 Elsevier. B) Mechanism of NIR-activated photocatalysis (ET:energyt ransfer).…”

Section: General Commentsmentioning

confidence: 99%

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Thermo‐Photocatalysis: Environmental and Energy Applications

et al. 2019

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Smart Photocatalysts in Water Remediation

Serrà

2022

Photocatalysts and Electrocatalysts in Water Remediation

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Inkjet Printed Large Area Multifunctional Smart Windows

Cai

Darmawan

Cheng

et al. 2017

Advanced Energy Materials

276

162

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Multifunctional smart windows are successfully fabricated by assembling inkjet printed CeO 2 /TiO 2 and WO 3 /poly(3,4-ethylenedioxythiophene)poly(styrene sulfonate) films as the anode and cathode, respectively. Large optical modulation (more than 70% at 633 nm), fast switching (12.7/15.8 s), high coloration efficiency (108.9 cm 2 C −1 ), and excellent bistability are achieved by the assembled smart windows. The multifunctional smart window not only can be used as typical electrochromic window, which can change its color to dynamically control the solar radiation transmittance through windows or protect privacy during the day, but also can be used as energy-storage device simultaneously. The designed smart window releases the stored energy to light the bulbs and power other electronic devices at night while its color gradually reverts to transparent state. Moreover, the level of stored energy can be monitored via the visually detectable reversible color variation of the window. The fascinating multifunctional smart windows exhibit promising features for a wide range of applications in buildings, airplanes, automobiles, etc.

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A novel thermophotocatalyst of mixed-phase cerium oxide (CeO2/Ce2O3) homocomposite nanostructure: Role of interface and oxygen vacancies

Cited by 134 publications

References 38 publications

Thermo‐Photocatalysis: Environmental and Energy Applications

Thermo‐Photocatalysis: Environmental and Energy Applications

Smart Photocatalysts in Water Remediation

Inkjet Printed Large Area Multifunctional Smart Windows

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