The recovery performance of immiscible
and miscible CO2 huff-and-puff processes for enhanced oil
recovery (EOR) in a light
crude oil sample was experimentally investigated. The minimum miscibility
pressure (MMP) of the original light crude oil–CO2 system was determined by means of the vanishing interfacial tension
technique and found to be MMP = 9.18 MPa. Then, the solubility of
the CO2 in the light crude oil and oil swelling factor
due to the CO2 dissolution in the oil phase were determined
at T = 30 °C and various equilibrium pressures
ranging from atmospheric pressure to P
eq = 12.55 MPa. Later, series of immiscible and miscible CO2 huff-and-puff tests were designed and carried out at various operating
pressures (i.e., P
op = 5.38–10.34
MPa). The results of the experiments showed that for secondary CO2 huff-and-puff tests performed at the operating pressures
below the MMP, the ultimate oil recovery factor is quite low. It was
also found that in immiscible CO2 huff-and-puff (i.e., P
op < MMP) scenarios, the oil recovery factor
substantially increased as the operating pressure approached near-miscible
conditions. The oil recovery factor almost reached its maximum value
at operating pressure near MMP (i.e., miscible condition), and further
increase of operating pressure beyond MMP did not improve the recovery
factor at all. The tertiary mode of miscible CO2 huff-and-puff
was also examined, and it was revealed that the oil recovery is significantly
improved after a waterflooding process. The oil recovery mechanisms
during the CO2 huff-and-puff were mainly recognized to
be interfacial tension reduction, oil swelling, and extraction of
lighter components by CO2, especially during miscible CO2 injections. In addition, the average asphaltene content of
produced oil and the permeability reduction of the porous medium as
a result of asphaltene precipitation were measured in each test. It
was found that the amount of precipitated asphaltene in the porous
medium as well as permeability reduction are considerably higher in
near-miscible and miscible CO2 huff-and-puff tests compared
to those in immiscible cases. The compositional analysis of remaining
oil from CO2 huff-and-puff tests at immiscible and miscible
conditions also showed that lighter components of oil are extracted
by CO2, leading the remaining oil to become heavier with
greater amounts of heavy hydrocarbons (i.e., C30+). However,
it was observed that the extraction of lighter components during miscible
injection processes is more predominant than that during immiscible
injections, resulting in the production of higher quality oil.