Aims. Modeling of absorption features in the high resolution XMM-Newton Reflection Grating Spectrometer data. Methods. X-ray spectral analysis and modeling using the SRON (HEA Division, Netherlands Institute for Space Research) software SPEX version 2.05.04 .Results. We present a reanalysis of XMM-Newton Reflection Grating Spectrometer data of the classical nova V2491 Cyg obtained from two different pointings, 40 d and 50 d after outburst. We aim to model absorption components in the high resolution spectra independently from the continuum model. In order to model the complex absorption, we are utilizing hot collisionally ionized absorber models along with interstellar absorption (of gas and dust origin separately) that we discuss in the light of observations. For an adequate approximation, and ease of fitting procedures we use a blackbody model for the continuum. We find blackbody temperatures in a range 61-91 eV yielding a white dwarf (WD) mass of 1.15-1.3 M assuming this range is the maximum temperature achieved during the H-burning phase. We derive two different hot absorber components from our fits with blueshifts yielding 2900-3800 km s −1 for the first (day 40) and 2600-3600 km s −1 for the second observation 50 days after outburst consistent with ejecta/wind speeds. The two collisionally ionized hot absorption components have temperatures kT 1 1.0 − 3.6 keV and kT 2 0.4 − 0.87 keV with rms velocities σ v1 ∼ 872 km/s and σ v2 ∼ 56 km/s. These are consistent with shock temperatures in the X-ray wavelengths. V2491 Cyg shows signature of H-burning with underabundant carbon C/C =0.3-0.5, and enhanced nitrogen N/N =5-7 and oxygen O/O =16-43. The high oxygen overabundance hints at a C-O WD. We find the equivalent hydrogen column density of the hot collisionally ionized (in equilibrium) absorbers in a range (0.6-18.0)×10 23 cm −2 and (2.0-5.3)×10 23 cm −2 on days 40 and 50 after outburst, respectively. Our fits yield the most adequate χ 2 ν (range 1.8-2.9) up-to-date obtained for the modeling of high resolution X-ray data of V2491 Cyg. An additional photoionized absorber (third intrinsic absorber component) originating in the shell/ejecta improves the model fits with χ 2 ν in a range 1.7-2.5, but shows only (1-0.1)% of the absorption by the collisionaly-ionized hot gas. Our analysis reveals a second blackbody component on day 50 with effective temperature 120-131 eV and effective radius about 10% of the WD which may indicate the onset of magnetic accretion.