This study explored the effect of different cerium oxide abrasive particle sizes in chemical mechanical planarization of 200 mm blanket plasma-enhanced tetraethylorthosilicate wafers. All polishing experiments were done with a polisher and tribometer capable of measuring shear force and down force in real-time. Coefficient of friction and removal rate were found to correlate well with the slurry median particle size distribution. Removal rate modeling based on particle size was explored to support the interpretation of the experimental results.Shallow trench isolation ͑STI͒ is the preferred method of isolation for high-volume integrated circuit ͑IC͒ manufacturing with active device features in the deep submicrometer regime. During IC fabrication, STI incorporates silicon dioxide as the insulator and silicon nitride as the stopping layer. 1 In STI chemical mechanical planarization ͑CMP͒, cerium-oxide-based slurries are commonly used due to their high oxide-to-nitride removal rate selectivity. 2 Recent studies on silicon dioxide and silicon nitride CMP using ceria abrasive slurries have focused on the chemical aspect of the polishing process. 3-7 Generally speaking, cerium oxide slurry is a relatively new formulation compared to the more well-known silicaand alumina-based slurries. Compared to the extensive effort spent on the chemical aspects of the ceria abrasive slurry polishing, there is minimal published work on the effect of cerium oxide particle size in dielectric CMP.This paper investigates the coefficient of friction ͑COF͒ and removal rate of 200 mm blanket plasma-enhanced tetraethylorthosilicate ͑PETEOS͒ wafers using cerium-oxide-based slurries having four different particle size distributions. Wafers were polished using Araca APD-500 polisher and tribometer to measure the shear force and down force in real-time. Removal rate and COF of each slurry are then analyzed. Furthermore, removal rate modeling based on elastic-plastic microcontact mechanics and abrasive wear theory is explored to help interpret the experimental results.
ExperimentalFour cerium-oxide-based slurries with different particle sizes ͑summarized in Table I͒ were used to polish 200 mm blanket PETEOS wafers. D 50 and D 99 are defined as the size of the particle on the 50th and 99th percentiles of the total solid weight fraction, respectively. In all cases, the fraction of solid weight content of all slurries, X w , was 0.01. Polishing was performed on the Araca APD-500 polisher, which was capable of measuring friction force and actual down force in real-time during polishing. The polisher and its associated accessories have been described in detail elsewhere. 1,8 In this study, the data acquisition rate for shear force and down force measurement was set at 1000 Hz. For each slurry, five blanket PETEOS wafers were polished for 1 min on a 500 mm IC1000 A2 concentric groove pad manufactured by Rohm and Haas Electronic Materials. Polishing pressure and sliding velocity were kept constant at 3 psi and 1.37 m/s ͑a combination of 93 rpm for the ...