This paper analyses
the working principles of hybrid thermoelectric
photovoltaic generators under negative illumination (also referred
to as thermoradiative configuration). These kinds of systems combine
a thermoradiative photovoltaic cell (TR-PV cell) and a thermoelectric
generator (TEG), placed in thermal contact with each other. In this
configuration, the TR-PV part cools while irradiating toward the cold
sky. For this reason, in addition to the generation of electrical
output, the cell can set a difference of temperature (ΔT) across the TEG legs. A theoretical model describing the
behavior of these kinds of hybrid devices is reported as a function
of the emitter energy gap and temperature, the sky temperature, and
the ΔT across the TEG. In analogy with the
positive illumination case, the key parameter is found to be the cell
temperature sensitivity, which sets the convenience of the hybrid
approach. The results show that while the hybrid power density is
in general smaller than the sole TR-PV case, a wide window of positive
efficiency gains exists. This is possible because the outgoing power
density varies with the cell temperature, in contrast with the positive
illumination case where the incoming power density is fixed by the
temperature of the Sun. This work sets the first theoretical attempt
to understand the convenience of TR-hybrid thermoelectric–photovoltaic
generators (TR-HTEPVG), quantitatively assessing the suitability of
these novel kinds of devices.