We designed and synthesized dimeric imidazo[1, 5-a]pyridines possessing various aryl groups at 1,1'-positions. The solution of these derivatives exhibited fluorescence emission in wavelength range of 487-512 nm. The fluorescence emissions were slightly red-shifted under acidic condition by addition of trifluoroacetic acid. Furthermore, the original fluorescence spectra were observed after the addition of triethylamine as a base.[a] Prof.