2018
DOI: 10.1021/acs.jpclett.8b00858
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A Rechargeable Hydrogen Battery

Abstract: We utilize proton-coupled electron transfer in hydrogen storage molecules to unlock a rechargeable battery chemistry based on the cleanest chemical energy carrier molecule, hydrogen. Electrochemical, spectroscopic, and spectroelectrochemical analyses evidence the participation of protons during charge-discharge chemistry and extended cycling. In an era of anthropogenic global climate change and paramount pollution, a battery concept based on a virtually nonpolluting energy carrier molecule demonstrates distinc… Show more

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Cited by 26 publications
(19 citation statements)
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“…However, when considering the assembled full cells by using proton cathodes, the achieved rate and cycling stability of the reported proton full cells are still inferior to some high-performance aqueous batteries. ,, For instance, Ji and co-workers’ full cells with CuFe-TBA/WO 3 and CuFe-TBA/MoO 3 battery systems showed a poor cycle life with a capacity retention of 74% and 85% after 1000 cycles, respectively, although outstanding reactions still occurred in the cathodes. , Wang and co-workers proposed a MnO 2 /PTO proton full battery that delivered a high power density of 30.8 kW kg –1 , but with a severe capacity decay of 43% after 5000 cycles . In fact, only a limited number of APB full cells have been successfully demonstrated to date, which is primarily ascribed to the lack of stable proton electrodes in acidic electrolytes. ,, Therefore, it is very necessary to explore novel proton full cells with excellent performance for exerting the advantages of both proton cathode and anode, which are of paramount importance to their realistic applications.…”
Section: Introductionmentioning
confidence: 99%
“…However, when considering the assembled full cells by using proton cathodes, the achieved rate and cycling stability of the reported proton full cells are still inferior to some high-performance aqueous batteries. ,, For instance, Ji and co-workers’ full cells with CuFe-TBA/WO 3 and CuFe-TBA/MoO 3 battery systems showed a poor cycle life with a capacity retention of 74% and 85% after 1000 cycles, respectively, although outstanding reactions still occurred in the cathodes. , Wang and co-workers proposed a MnO 2 /PTO proton full battery that delivered a high power density of 30.8 kW kg –1 , but with a severe capacity decay of 43% after 5000 cycles . In fact, only a limited number of APB full cells have been successfully demonstrated to date, which is primarily ascribed to the lack of stable proton electrodes in acidic electrolytes. ,, Therefore, it is very necessary to explore novel proton full cells with excellent performance for exerting the advantages of both proton cathode and anode, which are of paramount importance to their realistic applications.…”
Section: Introductionmentioning
confidence: 99%
“…Recently, we have successfully demonstrated a new battery chemistry for the grid-scale energy storage by the coupling of electrocatalytic hydrogen gas anode with transition-metal oxide/hydroxide cathodes. , Taking advantages of the low overpotential, fast kinetics, and high stability of the hydrogen gas anode governed by hydrogen evolution and oxidation reactions (HER and HOR), , the demonstrated manganese–hydrogen and nickel–hydrogen batteries showed reasonable energy density, fast charge/discharge rates, and long cycle life. Their advantages were also compared with other rechargeable hydrogen technologies such as formate-based rechargeable hydrogen batteries , and proton-coupled electron transfer hydrogen batteries . The exciting characteristics of the rechargeable hydrogen batteries inspire us to explore new battery systems to enrich the hydrogen battery chemistry.…”
mentioning
confidence: 99%
“…The high average CE of ∼99.5% for the entire cycling duration indicates the efficient utilization of the electrical charge. Moreover, the LMO-H cell exhibits superior rate and cycling performance than some other hydrogen coupled batteries ,, (Table S1). The capacity decay of the LMO-H cell is derived from the instability of the LMO cathode, which is a well-known phenomenon involving the dissolution of Mn or the Jahn–Teller distortion of the LMO structure .…”
mentioning
confidence: 99%
“…Ion‐exchange process for stabilizing the electronic charges is important for the electrochemical energy storage; thus it could be achieved by active redox materials in the case of batteries, surface pseudocapacitance in supercapacitors 3‐5 . Proton exchangeable fuel cells have also gained equivalent importance in the field of sustainable electrochemical energy storage 6,7 . Li‐rich transition metal oxides, metal—O 2 /CO 2 cathodes have also been extensively studied as cathodes for lithium ion batteries (LIBs) 8 .…”
Section: Introductionmentioning
confidence: 99%