The present study aimed to assess and classify energy-environmental efficiency levels to reduce greenhouse gas emissions in the production, commercialization, and use of biofuels certified by the Brazilian National Biofuel Policy (RenovaBio). The parameters of the level of energy-environmental efficiency were standardized and categorized according to the Energy-Environmental Efficiency Rating (E-EER). The rating scale varied between lower efficiency (D) and high efficiency + (highest efficiency A+). The classification method with the J48 decision tree and naive Bayes algorithms was used to predict the models. The classification of the E-EER scores using a decision tree using the J48 algorithm and Bayesian classifiers using the naive Bayes algorithm produced decision tree models efficient at estimating the efficiency level of Brazilian ethanol producers and importers certified by the RenovaBio. The rules generated by the models can assess the level classes (efficiency scores) according to the scale discretized into high efficiency (Classification A), average efficiency (Classification B), and standard efficiency (Classification C). These results might generate an ethanol energy-environmental efficiency label for the end consumers and resellers of the product, to assist in making a purchase decision concerning its performance. The best classification model was naive Bayes, compared to the J48 decision tree. The classification of the Energy Efficiency Note levels using the naive Bayes algorithm produced a model capable of estimating the efficiency level of Brazilian ethanol to create labels.The production of biofuel from sugarcane is supported by the National Agency of Petroleum, Natural Gas and Biofuels' (ANP) sustainable development programs to achieve goals to reduce greenhouse gas emissions. Therefore, annual national targets were developed by the Brazilian National Biofuel Policy (RenovaBio) [12,15]. These goals are established in units of Decarbonization Credits (CBios) calculated from annual mandatory targets defined individually for each producer and distributor according to their participation in the fossil fuel market [12,16,[18][19][20][21].The certification of biofuel production assigns different marks to each biofuel producer and importer, in a value inversely related to the carbon amount of biofuel produced. The note reflects the individual contribution of each producing agent to mitigate a specific amount of GHG concerning its fossil substitute (in tons of CO 2 equivalent). The total emission is compared with that of the equivalent fossil fuel (gasoline, for ethanol), resulting in a final score (Energy-Environmental Efficiency Rating), characterizing the mitigation of emissions. This note generates CBios for biofuel producers and importers; with the decarbonization of the Brazilian energy matrix, there is a mechanism for the commercialization of these CBios linked to the carbon intensity of biofuels [2,12,16,18].The incentive to reduce pollutant emissions in the biofuel chain goes far beyond the use o...