This work examines the potential of some of the Gulf Cooperation Council countries (GCC) (Saudi Arabia (KSA), the United Arab Emirates (UAE), Qatar (QA), Bahrain (BH), Oman (OM)), Yemen (YE), Iraq (IQ), and Jordan (JO) to use their abundant solar radiation to generate electricity through PV technology. The study is structured to help decision-makers access the necessary data related to the status of solar-energy infrastructure and power production in the study region. The study investigates current efforts to establish PV technology and the challenges hindering the development of this technology. These efforts and challenges are then benchmarked against their status in Australia, which has climate and landscape conditions similar to those of the countries in the study region. It was found that Australia is successfully adopting solar energy in households and industrial locations despite its historical reliance on fossil fuels for energy production. This offers a potential avenue for replicating the Australian model of PV development in the study region. This work also addresses the effect of natural and anthropogenic aerosols on the performance of the PV panels. Meanwhile, it also proposes a conceptual model to help local governments and decision-makers in adopting solar-energy projects in the study region. Additionally, a preliminary carbon-footprint analysis of avoided emissions from PV energy utilization compared to national grid intensity was performed for each country. Findings show that the countries in the study region have great potential for using solar energy to gradually replace fossil fuels and protect the environment. It is observed that more hours of daylight and clear-to-scattered cloud coverage help increase solar irradiance near the ground all year around. Dust and aerosol loadings, however, were found to greatly reduce solar irradiance over the GCC area, especially during large dust events. Despite the high potential for harvesting solar energy in the study region, only a handful of PV plants and infrastructural facilities have been established, mostly in the KSA, the UAE, and Jordan. It was found that there is a critical need to put in place regulations, policies, and near-future vision to support solar energy generation and reduce reliance on fossil fuels for electricity production.