2022
DOI: 10.1177/87560879221088939
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A review on microphase separation measurement techniques for polyurethanes

Abstract: Polyurethanes (PUs) microstructure and characteristics is strongly affected by microphase separation that arises from the thermodynamic immiscibility between the hard and soft segments. The extent of phase separation as well as the morphology and size of the separated phase governs their mechanical, electrical, thermal, and functional properties. This review: (1) provides an insight into how phase separation affects PU properties, (2) explains methods used to study PU phase separation. We review approaches fro… Show more

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Cited by 24 publications
(17 citation statements)
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“…Due to the influential role of phase separation on PU properties, a myriad of approaches including Fourier‐transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), scanning electron and transmission electron microscopy (SEM and TEM), small angle x‐ray scattering (SAXS), and so forth have been employed to study the microphase separation of PUs 35,36 …”
Section: Polyurethanesmentioning
confidence: 99%
See 1 more Smart Citation
“…Due to the influential role of phase separation on PU properties, a myriad of approaches including Fourier‐transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), scanning electron and transmission electron microscopy (SEM and TEM), small angle x‐ray scattering (SAXS), and so forth have been employed to study the microphase separation of PUs 35,36 …”
Section: Polyurethanesmentioning
confidence: 99%
“…34 Due to the influential role of phase separation on PU properties, a myriad of approaches including Fouriertransform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), scanning electron and transmission electron microscopy (SEM and TEM), small angle x-ray scattering (SAXS), and so forth have been employed to study the microphase separation of PUs. 35,36 As a synthetic polymer, the most significant feature of PU is adjustability. PUs can be fabricated with different hard and soft segments and processing parameters to represent versatile properties and to be appropriate for various applications.…”
Section: Polyurethanesmentioning
confidence: 99%
“…When rigid segments segregate from the flexible segment, the final PU increases its degree of crystallinity. However, the crystallinity also depends on other factors, such as the symmetry or the nature of both the diisocyanate and the chain extender, as well as the preparation procedure [ 4 , 12 , 14 , 15 , 16 , 17 ]. The melting point of the final PU is also affected by the composition of the rigid segment; in particular, the melting temperature increases with the content of the rigid segment.…”
Section: Introductionmentioning
confidence: 99%
“…In contrast, the weaker hydrogen bonding between urethane-ether or urethane-ester groups gives rise to phase mixing. 10 Thus, the proportion of hydrogen bonds formed between the HS (NH…O C) might be used as a measure of the extent of phase separation. The fraction of hydrogen bonds between the hard and SS (NH…O) represents the extent of phase mixing between hard and soft segments.…”
Section: Introductionmentioning
confidence: 99%
“…The strongest hydrogen bonding between urethane–urethane groups is responsible for the microphase separation. In contrast, the weaker hydrogen bonding between urethane–ether or urethane–ester groups gives rise to phase mixing 10 . Thus, the proportion of hydrogen bonds formed between the HS (NH…OC) might be used as a measure of the extent of phase separation.…”
Section: Introductionmentioning
confidence: 99%