A review on recent advances in hierarchically porous metal and metal oxide nanostructures as electrode materials for supercapacitors and non-enzymatic glucose sensors

Hassan, Israr Ul; Salim, Hiba; Naikoo, Gowhar A.; Awan, Tasbiha; Dar, Riyaz Ahmad; Arshad, Fareeha; Tabidi, Mohammed A.; Das, Ratnesh; Ahmed, Waqar; Asiri, Abdullah M.; Qurashi, Ahsanulhaq

doi:10.1016/j.jscs.2021.101228

Cited by 55 publications

(35 citation statements)

References 129 publications

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“…Finally, the third generation eliminates the need for a reaction media by enzyme immobilization on the electrode surface, then glucose is oxidized directly by the electrode. However, the second and third generations present problems in terms of electrons transfer and poor reproducibility [4][5][6][7].…”

Section: Introductionmentioning

confidence: 99%

Non-Enzymatic Amperometric Glucose Screen-Printed Sensors Based on Copper and Copper Oxide Particles

et al. 2021

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Non-enzymatic amperometric glucose sensors have gained much attention in the past decade because of the better chemical and thermal stability and biocompatibility compared to conventional sensors based on the use of biomolecules. This study focuses on a novel copper and copper oxide-based glucose sensor synthesized by an electrodeposition technique through a rigorous protocol which reports an excellent analytical performance due to its structure and its increased active area. In addition, the linear response range, detection limit and sensitivity were 0.5–5.0 mmol L−1, 0.002 mmol L−1, 904 μA mmol−1 L−1 cm−2, respectively. Results show a reliable electrode as it is chemically stable, exhibits rapid and excellent sensitivity, and it is not significantly affected by coexisting species present in the blood samples; furthermore, it reports a maximum relative standard deviation error (RSD) of 6%, and showed long operating life as the electrode was used for thousand measurements of 4.0 mmol L−1 glucose solution during three days.

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Section: Introductionmentioning

confidence: 99%

Non-Enzymatic Amperometric Glucose Screen-Printed Sensors Based on Copper and Copper Oxide Particles

et al. 2021

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“…Metal oxides have gained widespread popularity in recent decades because of their unusual electrocatalytic activity and are used in many electrochemical devices ( Hassan et al, 2021 ). As discussed before, metal oxides, including Co, Ni, Zn, Cu, Fe, Mn, Ti, Rh, Ir, Pt, Pd, and Au have proven to be promising elements for glucose oxidation in glucose sensing devices.…”

Section: Advantages and Disadvantages Of Negsmentioning

confidence: 99%

“…In particular, considerable consideration has been put forward to fabricate highly efficient materials to improve sensors’ performance by tailoring their shape, size, composition, adsorption capacity, electron transfer properties, and specific surface area. Over the past couple of decades, various metal and metal oxide materials have been employed for glucose sensing applications ( Toghill and Compton, 2010 ; Guler and Dilmac, 2019 ; Hossain and Slaughter, 2020 ; Hassan et al, 2021 )–( Toghill and Compton, 2010 ; Guler and Dilmac, 2019 ; Hossain and Slaughter, 2020 ; Hassan et al, 2021 ). Nanomaterials of noble metals (Ag, Au, Pd, and Pt) ( Wang et al, 2014 ; Baghayeri et al, 2018a ; Ma et al, 2019 ) were considered excellent choices for constructing NEG sensors because of their high efficiency in glucose electrooxidation.…”

Section: Introductionmentioning

confidence: 99%

Recent Advances in Non-Enzymatic Glucose Sensors Based on Metal and Metal Oxide Nanostructures for Diabetes Management- A Review

et al. 2021

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There is an undeniable growing number of diabetes cases worldwide that have received widespread global attention by many pharmaceutical and clinical industries to develop better functioning glucose sensing devices. This has called for an unprecedented demand to develop highly efficient, stable, selective, and sensitive non-enzymatic glucose sensors (NEGS). Interestingly, many novel materials have shown the promising potential of directly detecting glucose in the blood and fluids. This review exclusively encompasses the electrochemical detection of glucose and its mechanism based on various metal-based materials such as cobalt (Co), nickel (Ni), zinc (Zn), copper (Cu), iron (Fe), manganese (Mn), titanium (Ti), iridium (Ir), and rhodium (Rh). Multiple aspects of these metals and their oxides were explored vis-à-vis their performance in glucose detection. The direct glucose oxidation via metallic redox centres is explained by the chemisorption model and the incipient hydrous oxide/adatom mediator (IHOAM) model. The glucose electrooxidation reactions on the electrode surface were elucidated by equations. Furthermore, it was explored that an effective detection of glucose depends on the aspect ratio, surface morphology, active sites, structures, and catalytic activity of nanomaterials, which plays an indispensable role in designing efficient NEGS. The challenges and possible solutions for advancing NEGS have been summarized.

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“…The specific size of nanostructured materials, such as nanoparticles, can change their magnetic, conductive, chemical and electronic properties [181,183,184]. Particularly, due to the unique physical and chemical properties of metal oxide nanoparticles, a wide range of applications has been investigated in materials chemistry, medicine, agriculture, information technology, the biomedical field, optics, electronics, catalysis, environmental fields, energy applications [185][186][187][188][189] and in the treatment of water and effluents, among others [190][191][192][193]. Increased surface area in nanostructured metal oxides leads to increased reactivity [194].…”

Section: Metallic Nanoparticles and Nanostructured Metal Oxidesmentioning

confidence: 99%

Conversion of Plastic Waste into Supports for Nanostructured Heterogeneous Catalysts: Application in Environmental Remediation

et al. 2021

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Plastics are ubiquitous in our society and are used in many industries, such as packaging, electronics, the automotive industry, and medical and health sectors, and plastic waste is among the types of waste of higher environmental concern. The increase in the amount of plastic waste produced daily has increased environmental problems, such as pollution by micro-plastics, contamination of the food chain, biodiversity degradation and economic losses. The selective and efficient conversion of plastic waste for applications in environmental remediation, such as by obtaining composites, is a strategy of the scientific community for the recovery of plastic waste. The development of polymeric supports for efficient, sustainable, and low-cost heterogeneous catalysts for the treatment of organic/inorganic contaminants is highly desirable yet still a great challenge; this will be the main focus of this work. Common commercial polymers, like polystyrene, polypropylene, polyethylene therephthalate, polyethylene and polyvinyl chloride, are addressed herein, as are their main physicochemical properties, such as molecular mass, degree of crystallinity and others. Additionally, we discuss the environmental and health risks of plastic debris and the main recycling technologies as well as their issues and environmental impact. The use of nanomaterials raises concerns about toxicity and reinforces the need to apply supports; this means that the recycling of plastics in this way may tackle two issues. Finally, we dissert about the advances in turning plastic waste into support for nanocatalysts for environmental remediation, mainly metal and metal oxide nanoparticles.

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A review on recent advances in hierarchically porous metal and metal oxide nanostructures as electrode materials for supercapacitors and non-enzymatic glucose sensors

Cited by 55 publications

References 129 publications

Non-Enzymatic Amperometric Glucose Screen-Printed Sensors Based on Copper and Copper Oxide Particles

Non-Enzymatic Amperometric Glucose Screen-Printed Sensors Based on Copper and Copper Oxide Particles

Recent Advances in Non-Enzymatic Glucose Sensors Based on Metal and Metal Oxide Nanostructures for Diabetes Management- A Review

Conversion of Plastic Waste into Supports for Nanostructured Heterogeneous Catalysts: Application in Environmental Remediation

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