Several authigenic minerals were identified by XRD and SEM analyses in shallow sediments from the Southeast Hainan Basin, on the northern slope of South China Sea. These minerals include miscellaneous carbonates, sulphates, and framboidal pyrite, and this mineral assemblage indicates the existence of gas hydrates and a methane seep. The assemblage and fabric features of the minerals are similar to those identified in cold-seep sediments, which are thought to be related to microorganisms fostered by dissolved methane. Chemical composition of pore water shows that the concentrations of SO 2− 4 , Ca 2+ , Mg 2+ , and Sr 2+ decrease clearly, and the ratios of Mg 2+ to Ca 2+ and Sr 2+ to Ca 2+ increase sharply with depth. These geochemical properties are similar to those where gas hydrates occur in the world. All results seem to indicate clearly the presence of gas hydrates or deep water oil (gas) reservoirs underneath the seafloor.