A significant role of MoO3 on the optical, thermal, and radiation shielding characteristics of B2O3–P2O5–Li2O glasses

Alrowaili, Z.A.; Ali, Atif Mossad; Al-Baradi, Ateyyah M.; Al-Buriahi, M.S.; Wahab, E. A. Abdel; Shaaban, Kh. S.

doi:10.1007/s11082-021-03447-0

Cited by 96 publications

(4 citation statements)

References 72 publications

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“…Ali et al [14] studied the in uence of MoO 3 on PbO-Sb 2 O 3 -As 2 O 3 -MoO 3 glasses and concluded that the former and modi er role of MoO3 in these glasses based on its mol%. Alrowaili et al [15] prepared the , etc prepared glasses with various compositions containing the MoO 3 and con rmed that the glasses when incorporated with MoO 3 found better applications related to optical and shielding features. As a result, the union of borate with MoO 3 can result in the formation of glasses.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, physical, optical and structural studies of B2O3-CdO-Al2O3-PbF2 glasses modified with MoO3 ions

et al. 2022

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This manuscript deals with the preparation and detailed physical and structural study of B 2 O 3 -CdO-Al 2 O 3 -PbF 2 glasses reinforced with MoO 3 ions. With the addition of MoO 3 , the density and band gap values decreased while the refractive index increased, con rming the transformation of Mo 6+ ions to Mo 5+ ions and resulting in the generation of NBO's in these glasses. The FTIR spectra revealed the presence of different borate and aluminate units. The FTIR spectra also indicated the conversion of Mo 6+ ions to Mo 5+ ions. The effect of MoO 3 ions on Raman spectra was clearly visible and indicated the conversion of BO 4 to BO 3 units, increasing NBO's which helped to explain the density variation.

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Section: Introductionmentioning

confidence: 99%

Synthesis, physical, optical and structural studies of B2O3-CdO-Al2O3-PbF2 glasses modified with MoO3 ions

et al. 2022

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“…Lithium-ion batteries have been widely used in energy storage devices, which are currently one of the most promising technologies [20][21][22][23][24][25][26][27][28][29][30]. Lithium has also been utilized in special glasses and ceramics [31][32][33][34][35], as well as in wearable sensors [36][37][38] and pharmacology [39][40][41]. Our current knowledge of lithium and its compounds can be found in reviews [42][43][44][45][46][47][48][49][50][51] and the references therein.…”

Section: Introductionmentioning

confidence: 99%

A spin–orbit configuration interaction study of the low-lying electronic states of the diatomic lithium antimonide cation

Jiang

et al. 2023

J. Phys. B: At. Mol. Opt. Phys.

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High-level ab initio calculations were performed to determine the structural features, electronic characteristics, and transitional properties of LiSb+, which is a hitherto experimentally unknown diatomic cation. We acquired and evaluated potential energy curves, spectroscopic constants, and vibrational energy levels for low-lying Λ-S electronic states and their related Ω states. The spin-orbit coupling effect has a slight impact on these states. The transitional properties, such as transition dipole moments, Einstein coefficients, Franck-Condon factors and vibrational branching ratios, as well as the radiative lifetimes of transitions from excited Ω states to the ground state, have been identified and discussed. We anticipate that these prognostic results will act as guidelines for future research.

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“…The scientific community has recently focused on manufacturing and analyzing optical glass systems doped with heavy metal oxide (HMO) and its special applications in optics, photonic devices, and nuclear engineering [1][2][3][4][5]. Synthesis and characterization of new materials are important for several applications [6][7][8][9][10][11]. Furthermore, doping such substances with rare-earth (Re 3+ ) ions enhances their optical and electronic properties, good stability, and flexibility characteristics, allowing an intake of elements in their formulation to be accepted.…”

Section: Introductionmentioning

confidence: 99%

Enhanced linear and nonlinear optical properties of erbium/ytterbium lead phosphate glass by gamma irradiation for optoelectronics applications

et al. 2022

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Herein, this study intends to reveal the impact of gamma irradiation on the structural, linear, and nonlinear optical characteristics of 47P2O5−23Na2O−6Al2O3−22PbO−0.5Er2O3−1.5Yb2O3 glass. The Er/Yb-doped lead phosphate glass samples were produced using the traditional melt quenching procedure and then treated to different doses of gamma irradiation (0, 20, 50, and 100) kGy. The amorphous phase structure of the Er/Yb-doped lead phosphate glass samples was verified through XRD patterns. Also, the shift of the FTIR peaks due to the change in bond angles, and the change in the bond length of the P–O–P bridges means the glass network stability against radiation. With increasing irradiation dosages, the energy gap dropped from 4.11 eV to 3.42 eV and then enhanced to 3.48 at 100 kGy. At the same time, the Urbach energy enhanced from 10.23 eV to 37.03 eV. The oscillator energy Eo was found between 1.55 and 1.62 eV. Also, the dispersion energy Ed varied between 2.11 eV at 100 kGy and 2.71 eV at the dose of 50 kGy. The percentage of free carrier ions to effective mass (N/m*) is in the range (4.82–8.66) × 1047 cm3/g. Besides, the lattice dielectric constant ($${\varepsilon }_{l}$$ ε l ) increased from 5.54 to 6.63 as the gamma dosages increased. Furthermore, increasing gamma doses up to 50 kGy promotes susceptibility, which subsequently declines at 100 kGy, suggesting that increasing gamma doses over 50 kGy weakens polarizability potential. While the increasing gamma doses up to 50 kGy reduces the nonlinear refractive index and then improves at 100 kGy. Overall, the nonlinear and linear research revealed that Er/Yb lead phosphate glass is being used as a promising material for gain media and optical amplifiers.

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A significant role of MoO3 on the optical, thermal, and radiation shielding characteristics of B2O3–P2O5–Li2O glasses

Cited by 96 publications

References 72 publications

Synthesis, physical, optical and structural studies of B2O3-CdO-Al2O3-PbF2 glasses modified with MoO3 ions

Synthesis, physical, optical and structural studies of B2O3-CdO-Al2O3-PbF2 glasses modified with MoO3 ions

A spin–orbit configuration interaction study of the low-lying electronic states of the diatomic lithium antimonide cation

Enhanced linear and nonlinear optical properties of erbium/ytterbium lead phosphate glass by gamma irradiation for optoelectronics applications

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