2017
DOI: 10.1021/acs.estlett.7b00454
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A Simple Method for Quantifying Polycarbonate and Polyethylene Terephthalate Microplastics in Environmental Samples by Liquid Chromatography–Tandem Mass Spectrometry

Abstract: Microplastics (MPs) have frequently been found in the environment. However, studies of the quantification methods for MPs are still needed. Plastics are polymers with different degrees of polymerization. In this study, alkali-assisted thermal hydrolysis was applied to depolymerize two plastics containing ester groups, polycarbonate (PC) and polyethylene terephthalate (PET), in a pentanol or butanol system. By determining the concentrations of the depolymerized building block compounds, i.e., bisphenol A and p-… Show more

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Cited by 147 publications
(98 citation statements)
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“…Plastics always contain plastic additives such as pigments, stabilizers and plasticizers, flame retardants and so on to improve their mechanical and processing performances. A recent study quantified the microplastics through determining the concentration of additives in microplastics [36]. In that study, the alkali-assisted thermal hydrolysis was first applied to depolymerize polycarbonate (PC) and polyethylene terephthalate (PET) microplastics in a pentanol or butanol system.…”
Section: Identification and Quantification Of Microplasticsmentioning
confidence: 99%
“…Plastics always contain plastic additives such as pigments, stabilizers and plasticizers, flame retardants and so on to improve their mechanical and processing performances. A recent study quantified the microplastics through determining the concentration of additives in microplastics [36]. In that study, the alkali-assisted thermal hydrolysis was first applied to depolymerize polycarbonate (PC) and polyethylene terephthalate (PET) microplastics in a pentanol or butanol system.…”
Section: Identification and Quantification Of Microplasticsmentioning
confidence: 99%
“…Here, we focused on the MP identification and quantification methods. To identify and quantify MPs, several analytical methods such as optical/fluorescence microscopy [ 57 ], scanning electron microscopy (SEM), FTIR [ 58 , 59 ], Raman spectroscopy [ 60 ], thermogravimetric analysis [ 61 ], differential scanning calorimetry (DSC), and mass spectroscopy [ 62 , 63 ] have been used [ 24 , 64 , 65 ].…”
Section: Current Technologies Used For Mp Detection and Quantificamentioning
confidence: 99%
“…Typically, the statistics for plastic particles are counted manually under the microscope, but this is time-consuming and inaccurate. Wang et al developed a method for directly quantifying PC and PET microplastics in environments by depolymerizing these plastics and identifying emerging structural unit compounds (Wang, Zhang, Hou, & Sun, 2017). The method was successfully applied to sludge, marine sediments, indoor dust, mussel, and earthworm digestive residues.…”
Section: Quantification Of Microplasticsmentioning
confidence: 99%