with the state-of-the-art high voltage cathode batteries with theoretical specific energy of ≈600 Wh kg −1 . In addition, elemental sulfur is environmentally friendly, inexpensive, and abundant.The Li-S battery poses some challenges that need to be overcome. One of the major challenges of the Li-S battery is that it generally suffers from the shuttling of soluble polysulfide species (Li 2 S x , x = 4-8) during cycling, which results in a low Coulombic efficiency and reduces its cycle life, typically to less than 100 cycles. In addition, since sulfur [1] and lithium sulfide are electronic insulators, the electronic conductivity of the cathode typically has to be augmented by addition of a significant amount of conductive carbon. To overcome these issues, most efforts have been directed to prevent soluble polysulfides from shuttling, by encapsulation of sulfur with conducting membranes or porous structures, most recently through designing 3D cathode architechtures [30][31][32][33][34] or other sulfur hosts [35,36] which allow improved stability as well as fast kinetics. Among conductive polymers, polypyrrole has been widely investigated [20,26,28,37] owing to its high electronic conductivity, low cost of precursors, and ease of synthesis. However, studies of polypyrrole encapsulated sulfur composites have shown no major successes perhaps due to the presence of large pores (≈5 nm, Figure S1, Supporting Information) in the encapsulating polymer. In addition, encapsulated sulfur nanocomposites require dissolution of a certain amount of sulfur by organic solvents to provide a void space in order to accommodate the large volumetric expansion of sulfur upon lithiation. [26] Here, for the first time, we demonstrate a strategy to improve the stability of Li-S battery using a multilayer encapsulation of sulfur nanoparticles. To ensure an effective encapsulation of sulfur, the following coating layers are selected. We coat the sulfur nanoparticles with MnO 2 particles as the interior shell since it was demonstrated that soluble lithium polysulfide species can be easily oxidized to thiosulfate groups by MnO 2 particles. The thiosulfate groups formed on the surface of the MnO 2 are proposed to anchor long-chain polysulfides by catenating them to form polythionates and therefore catalyze their conversion to insoluble short-chain polysulfides which significantly minimizes the shuttle effect. [29] We use polypyrrole as the exterior shell since (a) its porous structure allows electrolyte uptake, (b) its flexible network supports and contains the inner MnO 2 shell during discharging where the volumetric expansion of sulfur occurs, and (c) its remarkable electronic conductivity Advancements in portable electronic devices and electric powered transportation has drawn more attention to high energy density batteries, especially lithium-sulfur batteries due to the low cost of sulfur and its high energy density. However, the lithium-sulfur battery is still quite far from commercialization mostly because of incompatibility between all ma...