This paper implements the parameter identification of ship roll motion based on vibration tests and the computational fluid dynamics (CFD) method. By applying sinusoidal moment excitations from a shaker, we successfully simulate the quasi-roll motion behavior of the ship model in the air. We conduct two vibration tests, including a constant-amplitude angular displacement test and a constant-amplitude angular velocity test, to identify the restoring moment and the damping moment coefficients of the quasi-roll motion. In addition, we perform the approximate equivalence of the fluid around the ship through the CFD method and the fluid-solid coupling technique. Thus, we obtain the hydrodynamic coefficients, such as the added mass moment of inertia and the equivalent damping, to accomplish the parameter identification of the ship's real roll motion. Finally, the accuracy of the identified parameters is verified by means of numerical simulations based on the Runge-Kutta method.