Although rail is one of the most sustainable transport systems, there is still room to reduce its energy demand. In particular, during the braking of DC powered trains, a significant amount of energy is wasted. The recent developments in energy storage system technologies, combined with the widely used technique of regenerative braking, can considerably increase energy saving. This paper explores this theme, quantifying the amount of braking energy that can be potentially recovered in a real case study, starting from the experimental data measured on-board train. A simplified numerical model of the recovery process has been implemented. Adopting it, the energy that can be saved, with one or two energy storage systems, has been quantified for each possible position along the track. The procedure allows to determine the optimal position. Further findings about the impact of voltage level on the efficiency of the recovery process have been reported. The optimal level of voltage has been determined, also considering the additional losses in the catenary, both during the traction and braking phase of the train. Moreover, it allows dimensioning of stationary storage systems considering two different energy management strategies and their impact on the peak of stored energy. The proposed approach will be presented with reference to the concrete case of a specific route on the Italian rail network, analyzing a train in normal commuter service and the obtained results will be discussed. In the best situation, about the 73% of the braking energy can be recovered.