In this work, we are introducing an innovative technique
to enhance
the CO2 foam stability by using a nanofoam stabilizer that
reduces the surfactant concentrations below the critical micelle concentration
(CMC). The core structure of our foam stabilizer consists of faujasite
zeolite nanoparticles (FAU) that are grafted with cationic surfactant,
cetyltrimethylammonium bromide (CTAB). The prepared nanomaterials
were fully characterized by an array of characterization techniques
to gain insight into their surface properties and stability. Then,
the foamability and foam stabilization properties of the CTAB, compared
with the physically mixed CTAB and neat FAU nanoparticles, and CTAB-grafted
FAU nanoparticle systems were evaluated at various surfactant concentrations
based on initial foam volume, half-life, liquid holdup, surface shear
viscosity, and bubble sizes. Furthermore, the CO2 foam
stabilization mechanisms of all foaming agents were investigated by
the dilational surface tension. Our results indicated that the CTAB-grafted
FAU nanoparticles were able to stabilize the liquid films of CO2 foam at low surfactant concentrations via surfactant coverage
on the surface of nanoparticles, which optimized the viscoelastic
and surface tension properties of CO2 foam. In fact, below
the CMC of CTAB (∼335 ppm), the initial foam volume and half-life
remained constant after the addition of the FAU nanoparticles, whereas
the foam properties were highly enhanced above the CMC (350–3000
ppm). Our foam stabilization results showed that the optimum stable
CO2 foam was generated by CTAB-grafted FAU nanoparticles
at a concentration of 1000 ppm (∼500 ppm grafted CTAB), which
had a half-life of 773 s, in contrast to the other systems that had
a half-life of less than 350 s at 500 ppm CTAB concentration. The
surface tension results showed that grafting 50 and 100 ppm CTAB on
FAU nanoparticles resulted in 60.20 and 51.52 mN/m initial dynamic
surface tension measurements, whereas the virgin CTAB solutions at
the same surfactant concentrations had initial dynamic surface tensions
of 69.78 and 60.44 mN/m, respectively. On the other hand, at a surfactant
concentration of 50 ppm (100 ppm CTAB-FAU nanoparticles), the viscoelastic
modulus was almost identical to the viscoelastic modulus measurement
at the CMC of CTAB. Interestingly, the CTAB-grafted FAU nanoparticles,
compared with the other systems, had almost 1.5–4 times higher
liquid holdup and formed smaller and homogeneous bubble sizes during
the first 360 s. Hence, the CTAB-grafted FAU nanoparticles could retard
the foam destabilization mechanisms, including foam bubble coalescence
and ripening effects, due to their ability to maximize the viscoelastic
modulus and reduce the surface tension at these low surfactant concentrations.
Our findings can provide an economical solution for implementing conventional
CO2 foams in enhanced oil recovery (EOR) applications while
hindering the agglomeration of nanoparticles.