A study of the electron impact induced retro‐diels‐alder process with selected 5,6,6a, 7,12,12a‐hexahydrobenzo[<i>a</i>]anthracenes

Bobenrieth, M. J.; Levy, Louis; Hass, J. Ronald

doi:10.1002/oms.1210190402

Cited by 4 publications

References 33 publications

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Mass Spectra of Double‐Bonded Groups

Gäumann

2009

Patai's Chemistry of Functional Groups

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An Introduction, to Warm Up The Localization of the C  C Double Bond: an Analytical Problem Ethylene: An Old Faithful The Pentene Story Heptene: The Other Story Alkenes: To Fill Some Gaps Acetone, Seemingly Simple Other Ketones: The More it Changes, the More It Is the Same Diels–Alder and Retro‐Diels–Alder Reactions Acknowledgments

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Mass Spectra of Double‐Bonded Groups

Gäumann

2009

Patai's Chemistry of Functional Groups

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Reaction of ammonia with accelerated benzoyl ions under multiple‐collison conditions in a triple quadrupole instrument

White

Tabet

Bursey

1987

Org. Mass Spectrom.

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The reaction of benzoyl ion with ammonia in multiple-collision conditions in the second quadrupole assembly of a triple quadrupole mass spectrometer at (laboratory) ion kinetic energies from 0 to 20 eV produced the even-electron ions [CsH5]', [C6H5NH3.(NH3),l+ ( m = 0 , l ) and [C6H5CONH3-(NH3),]+ (n = 0,1,2,3) and the odd-electron ions [CsH4NH3-(NH3),]+' (p = 0, I). Thermochemical information could not be obtained under multiple-collision conditions: both exothermic and endothermic reactions were observed, with no translational-energy onset measurable for the endothermic processes, nor decrease in the yield of the exothermic processes at high energies. The behaviour of cluster-ion intensities as pressure varied was qualitatively as expected. There are pressure and energy regions where spectra change little; if this feature were to be general, it would point to some utility for these conditions in qualitative analysis.

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The functional relationship scan in tandem mass spectrometry

Vincenti

Schwartz

Cooks

et al. 1988

Org. Mass Spectrom.

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A type of tandem mass spectrometric scan is described in which m, +, m,+ and m3, defined in terms of the process m, + + m, + + m3, are all varied while maintaining some prescribed relationship between them. The scan can be viewed as a variant upon the neutral loss scan in which the constant mass difference between parent and daughter ion masses is replaced by some other functional relationship. Specific examples of this scan are provided in two simple applications: (i) symmetrical proton-bound dimers are recognized using the functional scan m, = (m, + 1)/2; and (ii) symmetrical Diels-Alder adducts comprised of diene and dienophile of equal masses are recognized in mixtures using the scan function m2 = (1/2)m1.

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A study of the electron impact induced retro‐diels‐alder process with selected 5,6,6a, 7,12,12a‐hexahydrobenzo[a]anthracenes

Cited by 4 publications

References 33 publications

Mass Spectra of Double‐Bonded Groups

Mass Spectra of Double‐Bonded Groups

Reaction of ammonia with accelerated benzoyl ions under multiple‐collison conditions in a triple quadrupole instrument

The functional relationship scan in tandem mass spectrometry

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